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Perchlorate concentration was the highest in Chilean nitrate, ranging from 3.3 to 3.98%. [51] Perchlorate in the solid fertilizer ranged from 0.7 to 2.0 mg g −1, variation of less than a factor of 3 and it is estimated that sodium nitrate fertilizers derived from Chilean caliche contain approximately 0.5–2 mg g −1 of perchlorate anion. [74]
Sodium perchlorate is an inorganic compound with the chemical formula Na Cl O 4. It consists of sodium cations Na + and perchlorate anions ClO − 4. It is a white crystalline, hygroscopic solid that is highly soluble in water and ethanol. It is usually encountered as sodium perchlorate monohydrate NaClO 4 ·H 2 O.
Potassium perchlorate in crystal form. Potassium perchlorate is prepared industrially by treating an aqueous solution of sodium perchlorate with potassium chloride.This single precipitation reaction exploits the low solubility of KClO 4, which is about 1/100 as much as the solubility of NaClO 4 (209.6 g/100 mL at 25 °C).
Calcium perchlorate is a strong inorganic oxidizing agent, enhancing the combustion of other substances that can potentially lead to explosion. The perchlorate ion, ClO − 4, has a highly symmetrical tetrahedral structure that is strongly stabilized in solution by its low electron-donating proton-accepting power and its relatively low polarizability.
Hydronium perchlorate is produced by the reaction of anhydrous perchloric acid and water in a 1:1 molar ratio: [2]. HClO 4 + H 2 O → [H 3 O] + ClO − 4. A more analytically reliable method was reported using the macrocyclic Schiff base of sodium 2,6-diformyl-4-methylphenolate and 2,6-diformyl-4-methylphenol as a chelating agent to sequester Cu(II): transmetallation of the macrocycle with ...
Chlorine perchlorate is a chemical compound with the formula Cl 2 O 4. This chlorine oxide is an asymmetric oxide, with one chlorine atom in +1 oxidation state and the other +7, with proper formula ClOClO 3. It is produced by the photodimerization of chlorine dioxide (ClO 2) at room temperature by 436 nm ultraviolet light: [2] [3] [4] 2ClO 2 ...
Copper(II) perchlorate is an inorganic compound with the chemical formula Cu(ClO 4) 2 (H 2 O) x.The anhydrous solid is rarely encountered but several hydrates are known. Most important is the perchlorate salt of the aquo complex copper(II) perchlorate hexahydrate, [Cu(H 2 O) 6] 2+.
The chlorite ion adopts a bent molecular geometry, due to the effects of the lone pairs on the chlorine atom, with an O–Cl–O bond angle of 111° and Cl–O bond lengths of 156 pm. [1] Chlorite is the strongest oxidiser of the chlorine oxyanions on the basis of standard half cell potentials.