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C═C acyclic C═C monosub. alkenes 1645 medium 1,1-disub. alkenes 1655 medium cis-1,2-disub. alkenes 1660 medium trans-1,2-disub. alkenes 1675 medium trisub., tetrasub. alkenes 1670 weak conjugated C═C dienes 1600 strong 1650 strong with benzene ring 1625 strong with C═O 1600 strong C═C (both sp 2) any 1640–1680 medium aromatic C═C any
Heat capacity, c p: 106.3 J/(mol K) at –124 °C Liquid properties Std enthalpy change of formation, Δ f H o liquid –303.0 kJ/mol Standard molar entropy, S o liquid: 192.8 J/(mol K) Enthalpy of combustion, Δ c H o –2021 kJ/mol Heat capacity, c p: 144.4 J/(mol K) Gas properties Std enthalpy change of formation, Δ f H o gas –255 kJ/mol ...
In organic chemistry, a carbonyl group is a functional group with the formula C=O, composed of a carbon atom double-bonded to an oxygen atom, and it is divalent at the C atom. It is common to several classes of organic compounds (such as aldehydes , ketones and carboxylic acid ), as part of many larger functional groups.
Homonuclear 13 C-13 C coupling is normally only observed in samples that are enriched with 13 C. The range for one-bond 1 J(13 C, 13 C) is 50–130 Hz. Two-bond 2 J(13 C, 13 C) are near 10 Hz. The trends in J(1 H, 13 C) and J(13 C, 13 C) are similar, except that J(1 H, 13 C are smaller owing to the modest value of the 13 C nuclear magnetic
However, practically all hydrogen bonded to carbon atoms is 1 H in natural isotopic abundance samples, including any 13 C nuclei bonded to H atoms. In a 13 C spectrum with no decoupling at all, each of the 13 C signals is split according to how many H atoms that C atom is next to. In order to simplify the spectrum, 13 C NMR spectroscopy is most ...
Heteronuclear Single Quantum Coherence (HSQC) is a 2D NMR technique utilized for the detection of interactions between different types of nuclei which are separated by one bond, particularly a proton (1 H) and a heteronucleus such as carbon (13 C) or nitrogen (15 N). [17]
Heat capacity, c p: 0.212 J/(mol K) at −200°C Liquid properties Std enthalpy change of formation, Δ f H o liquid: −318.2 kJ/mol Standard molar entropy, S o liquid: 180 J/(mol K) Heat capacity, c p: 2.68 J/(gK) at 20°C-25°C Gas properties Std enthalpy change of formation, Δ f H o gas: −261.1 kJ/mol Standard molar entropy, S o gas: 333 ...
The superscript "3" indicates that a 1 H atom is coupled to another 1 H atom three bonds away, via H-C-C-H bonds. (Such H atoms bonded to neighbouring carbon atoms are termed vicinal ). [ 4 ] The magnitude of these couplings are generally smallest when the torsion angle is close to 90° and largest at angles of 0 and 180°.