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Such solutions are designated "spent acid," or "pickle liquor" especially when the hydrochloric acid is not completely consumed: Fe + 2 HCl → FeCl 2 + H 2. The production of ferric chloride involves the use of ferrous chloride. Ferrous chloride is also a byproduct from the production of titanium, since some titanium ores contain iron. [3]
When metallic iron (oxidation state 0) is placed in a solution of hydrochloric acid, iron(II) chloride is formed, with release of hydrogen gas, by the reaction Fe 0 + 2 H + → Fe 2+ + H 2. Iron(II) is oxidized by hydrogen peroxide to iron(III), forming a hydroxyl radical and a hydroxide ion in the process. This is the Fenton reaction.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Aqueous solutions of iron(III) chloride are also produced industrially from a number of iron precursors, including iron oxides: Fe 2 O 3 + 6 HCl + 9 H 2 O → 2 FeCl 3 (H 2 O) 6. In complementary route, iron metal can be oxidized by hydrochloric acid followed by chlorination: [10] Fe + 2 HCl → FeCl 2 + H 2 FeCl 2 + 0.5 Cl 2 + 6 H 2 O → FeCl ...
Hydrochloric acid is a strong inorganic acid that is used in many industrial processes such as refining metal. The application often determines the required product quality. [25] Hydrogen chloride, not hydrochloric acid, is used more widely in industrial organic chemistry, e.g. for vinyl chloride and dichloroethane. [8]
Iron(III) oxide is a product of the oxidation of iron. It can be prepared in the laboratory by electrolyzing a solution of sodium bicarbonate, an inert electrolyte, with an iron anode: 4 Fe + 3 O 2 + 2 H 2 O → 4 FeO(OH) The resulting hydrated iron(III) oxide, written here as FeO(OH), dehydrates around 200 °C. [18] [19] 2 FeO(OH) → Fe 2 O 3 ...
Iron shows the characteristic chemical properties of the transition metals, namely the ability to form variable oxidation states differing by steps of one and a very large coordination and organometallic chemistry: indeed, it was the discovery of an iron compound, ferrocene, that revolutionalized the latter field in the 1950s. [1]
Ferric EDTA can be used as a component for the Hoagland solution or the Long Ashton Nutrient Solution. [7] According to Jacobson (1951), [2] the stability of ferric EDTA was tested by adding 5 ppm iron, as the complex, to Hoagland's solution at various pH values. No loss of iron occurred below pH 6.