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Nicotinamide adenine dinucleotide phosphate, abbreviated NADP [1] [2] or, in older notation, TPN (triphosphopyridine nucleotide), is a cofactor used in anabolic reactions, such as the Calvin cycle and lipid and nucleic acid syntheses, which require NADPH as a reducing agent ('hydrogen source'). NADPH is the reduced form, whereas NADP + is the ...
In cyclic photophosphorylation, cytochrome b 6 f uses electrons and energy from PSI to create more ATP and to stop the production of NADPH. Cyclic phosphorylation is important to create ATP and maintain NADPH in the right proportion for the light-independent reactions. The net-reaction of all light-dependent reactions in oxygenic photosynthesis ...
These regulatory functions prevent the Calvin cycle from being respired to carbon dioxide. Energy (in the form of ATP) would be wasted in carrying out these reactions when they have no net productivity. [citation needed] The sum of reactions in the Calvin cycle is the following: [citation needed] 3 CO 2 + 6 NADPH + 9 ATP + 5 H
to NADPH. [19] Fd moves to carry an electron either to a lone thylakoid or to an enzyme that reduces NADP +. [19] Thylakoid membranes have one binding site for each function of Fd. [19] The main function of Fd is to carry an electron from the iron-sulfur complex to the enzyme ferredoxin– NADP + reductase. [19]
In contrast, the main function of NADPH is as a reducing agent in anabolism, with this coenzyme being involved in pathways such as fatty acid synthesis and photosynthesis. Since NADPH is needed to drive redox reactions as a strong reducing agent, the NADP + /NADPH ratio is kept very low.
The electron is eventually used to reduce the coenzyme NADP with an H + to NADPH (which has functions in the light-independent reaction); at that point, the path of that electron ends. The cyclic reaction is similar to that of the non-cyclic but differs in that it generates only ATP, and no reduced NADP (NADPH) is created.
Ferredoxin: NADP + reductase is the last enzyme in the transfer of electrons during photosynthesis from photosystem I to NADPH. [2] The NADPH is then used as a reducing equivalent in the reactions of the Calvin cycle. [2] Electron cycling from ferredoxin to NADPH only occurs in the light in part because FNR activity is inhibited in the dark. [11]
NADP + + 2H + + 2e-→ NADPH + H + This consumes the H + ions produced by the splitting of water, leading to a net production of 1/2O 2, ATP, and NADPH + H + with the consumption of solar photons and water. The concentration of NADPH in the chloroplast may help regulate which pathway electrons take through the light reactions.
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