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In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula −OH and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry , alcohols and carboxylic acids contain one or more hydroxy groups.
The hydroxyl radical, • HO, is the neutral form of the hydroxide ion (HO –). Hydroxyl radicals are highly reactive and consequently short-lived; however, they form an important part of radical chemistry .
In chemistry, an alcohol (from Arabic al-kuḥl 'the kohl'), [2] is a type of organic compound that carries at least one hydroxyl (−OH) functional group bound to a saturated carbon atom. [ 3 ] [ 4 ] Alcohols range from the simple, like methanol and ethanol , to complex, like sugars and cholesterol .
A diol is a chemical compound containing two hydroxyl groups (−OH groups). [1] An aliphatic diol may also be called a glycol. [2] This pairing of functional groups is pervasive, and many subcategories have been identified. They are used as protecting groups of carbonyl groups, making them essential in synthesis of organic chemistry. [3]
In chemistry, hydroxylation refers to the installation of a hydroxyl group (−OH) into an organic compound. Hydroxylations generate alcohols and phenols, which are very common functional groups. Hydroxylation confers some degree of water-solubility. Hydroxylation of a hydrocarbon is an oxidation, thus a step in degradation.
The first and second steps are electrophilic addition that breaks the aromatic ring in benzene (A) and forms two hydroxyl groups (–OH) in intermediate C. Later an ·OH grabs a hydrogen atom in one of the hydroxyl groups, producing a radical species (D) that is prone to undergo rearrangement to form a more stable radical (E).
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Structure of the hydroxyl (-OH) functional group. The suffix –ol is used in organic chemistry principally to form names of organic compounds containing the hydroxyl (–OH) group, mainly alcohols. The suffix was extracted from the word alcohol. The suffix also appears in some trivial names with reference to oils (from Latin oleum, oil).