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The Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1), where the negatively charged electron confined to an atomic shell encircles a small, positively charged atomic nucleus and where an electron jumps between orbits, is accompanied by an emitted or absorbed amount of electromagnetic energy (hν). [1]
The Bohr model of the chemical bond took into account the Coulomb repulsion - the electrons in the ring are at the maximum distance from each other. [2] Thus, according to this model, the methane molecule is a regular tetrahedron, in which center the carbon nucleus locates, and in the corners - the nucleus of hydrogen. The chemical bond between ...
The Bohr model of the Hydrogen atom. One of the earliest steps towards atomic physics was the recognition that matter was composed of atoms, in modern terms the basic unit of a chemical element. This theory was developed by John Dalton in the 18th century.
His proposals were based on the then current Bohr model of the atom, in which the electron shells were orbits at a fixed distance from the nucleus. Bohr's original configurations would seem strange to a present-day chemist: sulfur was given as 2.4.4.6 instead of 1s 2 2s 2 2p 6 3s 2 3p 4 (2.8.6). Bohr used 4 and 6 following Alfred Werner's 1893 ...
Example 3 — nitrogen oxides: Dalton was aware of three oxides of nitrogen: "nitrous oxide", "nitrous gas", and "nitric acid". [16] These compounds are known today as nitrous oxide, nitric oxide, and nitrogen dioxide respectively. "Nitrous oxide" is 63.3% nitrogen and 36.7% oxygen, which means it has 80 g of oxygen for every 140 g of nitrogen.
The principal quantum number was first created for use in the semiclassical Bohr model of the atom, distinguishing between different energy levels. With the development of modern quantum mechanics, the simple Bohr model was replaced with a more complex theory of atomic orbitals. However, the modern theory still requires the principal quantum ...
However, Bohr's model failed to account for the relative intensities of the spectral lines and it was unsuccessful in explaining the spectra of more complex atoms. [ 51 ] Chemical bonds between atoms were explained by Gilbert Newton Lewis , who in 1916 proposed that a covalent bond between two atoms is maintained by a pair of electrons shared ...
The azimuthal quantum number was carried over from the Bohr model of the atom, and was posited by Arnold Sommerfeld. [11] The Bohr model was derived from spectroscopic analysis of atoms in combination with the Rutherford atomic model. The lowest quantum level was found to have an angular momentum of zero.