Search results
Results from the WOW.Com Content Network
Two chemical reactions on it simultaneously produce formaldehyde: that shown above and the dehydrogenation reaction: CH 3 OH → CH 2 O + H 2 In principle, formaldehyde could be generated by oxidation of methane , but this route is not industrially viable because the methanol is more easily oxidized than methane.
A common method for hydroxymethylation involves the reaction of formaldehyde with active C-H and N-H bonds: R 3 C-H + CH 2 O → R 3 C-CH 2 OH R 2 N-H + CH 2 O → R 2 N-CH 2 OH. A typical active C-H bond is provided by a terminal acetylene [1] or the alpha protons of an aldehyde. [2]
The Eschweiler–Clarke reaction (also called the Eschweiler–Clarke methylation) is a chemical reaction whereby a primary (or secondary) amine is methylated using excess formic acid and formaldehyde. [1] [2] Reductive amination reactions such as this one will not produce quaternary ammonium salts, but instead will stop at the tertiary amine ...
Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters. The reaction mainly applies to primary and secondary alcohols. Secondary alcohols form ketones, while primary alcohols form aldehydes or carboxylic acids. [1] A variety of oxidants can be used.
Industrially, formaldehyde is produced by catalytic oxidation of methanol. The most commonly used catalysts are silver metal or a mixture of an iron oxide with molybdenum and/or vanadium . In the recently more commonly used Formox process using iron oxide and molybdenum and/or vanadium, methanol and oxygen react at 300-400°C to produce ...
The direct reaction between phenol and paraformaldehyde is possible via the Casiraghi formylation, [4] but other methods apply masked forms of formaldehyde, in part to limit the formation of phenol formaldehyde resins. Aldehydes are strongly deactivating and as such phenols typically only react once.
Phenol-formaldehyde resins, as a group, are formed by a step-growth polymerization reaction that can be either acid- or base-catalysed.Since formaldehyde exists predominantly in solution as a dynamic equilibrium of methylene glycol oligomers, the concentration of the reactive form of formaldehyde depends on temperature and pH.
Sodium formate is also unavoidably formed as a by-product in the final step of the pentaerythritol synthesis and in the crossed Cannizzaro reaction of formaldehyde with the aldol reaction product trimethylol acetaldehyde [3-hydroxy-2,2-bis(hydroxymethyl)propanal]. [2]