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Solid-phase epitaxy (SPE) is a transition between the amorphous and crystalline phases of a material. It is usually produced by depositing a film of amorphous material on a crystalline substrate, then heating it to crystallize the film. The single-crystal substrate serves as a template for crystal growth.
In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter : solid , liquid , and gas , and in rare cases, plasma .
A specialised group of PCMs that undergo a solid/solid phase transition with the associated absorption and release of large amounts of heat. These materials change their crystalline structure from one lattice configuration to another at a fixed and well-defined temperature, and the transformation can involve latent heats comparable to the most ...
An amorphous solid that exhibits a glass transition is called a glass. The reverse transition, achieved by supercooling a viscous liquid into the glass state, is called vitrification . The glass-transition temperature T g of a material characterizes the range of temperatures over which this glass transition occurs (as an experimental definition ...
An amorphous metal (also known as metallic glass, glassy metal, or shiny metal) is a solid metallic material, usually an alloy, with disordered atomic-scale structure. Most metals are crystalline in their solid state, which means they have a highly ordered arrangement of atoms. Amorphous metals are non-crystalline, and have a glass-like structure.
Crystallization occurs in two major steps. The first is nucleation , the appearance of a crystalline phase from either a supercooled liquid or a supersaturated solvent. The second step is known as crystal growth , which is the increase in the size of particles and leads to a crystal state.
Phase transitions (phase changes) that help describe polymorphism include polymorphic transitions as well as melting and vaporization transitions. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure."
A deeper eutectic or more rapid cooling will result in finer lamellae; as the size of an individual lamellum approaches zero, the system will instead retain its high-temperature structure. Two common cases of this include cooling a liquid to form an amorphous solid, and cooling eutectoid austenite to form martensite.
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