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The first constitutive equation (constitutive law) was developed by Robert Hooke and is known as Hooke's law.It deals with the case of linear elastic materials.Following this discovery, this type of equation, often called a "stress-strain relation" in this example, but also called a "constitutive assumption" or an "equation of state" was commonly used.
The compressibility factor at the critical point, which is defined as =, where the subscript indicates physical quantities measured at the critical point, is predicted to be a constant independent of substance by many equations of state. The table below for a selection of gases uses the following conventions:
Defining equation (physical chemistry) List of electromagnetism equations; List of equations in classical mechanics; List of equations in quantum mechanics; List of equations in wave theory; List of photonics equations; List of relativistic equations; Relativistic wave equations
In physics, there are equations in every field to relate physical quantities to each other and perform calculations. Entire handbooks of equations can only summarize most of the full subject, else are highly specialized within a certain field. Physics is derived of formulae only.
The constitutive relation is expressed as a linear first-order differential equation: = + ˙ This model represents a solid undergoing reversible, viscoelastic strain. Upon application of a constant stress, the material deforms at a decreasing rate, asymptotically approaching the steady-state strain.
In physics, transport phenomena are all irreversible processes of statistical nature stemming from the random continuous motion of molecules, mostly observed in fluids. Every aspect of transport phenomena is grounded in two primary concepts : the conservation laws, and the constitutive equations.
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
A governing equation may also be a state equation, an equation describing the state of the system, and thus actually be a constitutive equation that has "stepped up the ranks" because the model in question was not meant to include a time-dependent term in the equation.