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A pentachloride is a compound or ion that contains five chlorine atoms or ions. Common pentachlorides include: Antimony pentachloride, SbCl 5; Arsenic pentachloride, AsCl 5 ...
The mechanism of the above reaction has not been resolved, but it has been suggested that PCl 5 is found in its ionic form [PCl 4] + [PCl 6] − (tetrachlorophosphonium hexachlorophosphate(V)) and the reaction proceeds via nucleophilic attack of [PCl 4] + (tetrachlorophosphonium) by NH 3 (from [NH 4]Cl dissociation). [2]
This is unlike phosphorus pentachloride which exists as neutral PCl 5 molecules in the gas and liquid states but adopts the ionic form [PCl 4] + [PCl 6] − (tetrachlorophosphonium hexachlorophosphate(V)) in the solid state. The average bond lengths in the crystal structure of POCl 3 are 1.98 Å for P–Cl and 1.46 Å for P=O. [5]
The reaction of phosphorus pentoxide and PCl 5 produces POCl 3 : [18] [page needed] 6 PCl 5 + P 4 O 10 → 10 POCl 3. PCl 5 chlorinates nitrogen dioxide to form unstable nitryl chloride: PCl 5 + 2 NO 2 → PCl 3 + 2 NO 2 Cl 2 NO 2 Cl → 2 NO 2 + Cl 2. PCl 5 is a precursor for lithium hexafluorophosphate, LiPF 6.
Printable version; In other projects Appearance. move to sidebar hide. From Wikipedia, the free encyclopedia. Redirect page. Redirect to: Phosphorus pentachloride;
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Phosphorus pentachloride, phosphorus pentabromide, and phosphorus heptabromide are ionic in the solid and liquid states; PCl 5 is formulated as PCl 4 + PCl 6 –, but in contrast, PBr 5 is formulated as PBr 4 + Br −, and PBr 7 is formulated as PBr 4 + Br 3 −. They are widely used as chlorinating and brominating agents in organic chemistry.
HP-GL, short for Hewlett-Packard Graphics Language and often written as HPGL, is a printer control language created by Hewlett-Packard (HP). HP-GL was the primary printer control language used by HP plotters. [1]