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First, DMAP and acetic anhydride react in a pre-equilibrium reaction to form an ion pair of acetate and the acetylpyridinium ion. In the second step the alcohol adds to the acetylpyridinium, and elimination of pyridine forms an ester. Here the acetate acts as a base to remove the proton from the alcohol as it nucleophilically adds to the ...
4-Dimethylaminophenol (DMAP) is an aromatic compound containing both phenol and amine functional groups. It has the molecular formula C 8 H 11 NO. Uses
DMAP may refer to: Digital Media Access Protocol, a family of proprietary protocols by Apple; 4-Dimethylaminopyridine (CH 3) 2 NC 5 H 4 N), a derivative of pyridine; 4-Dimethylaminophenol (C 8 H 11 NO), an aromatic compound containing both phenol and amine functional groups; Data Management Advisory Panel, of the England school census
The Yamaguchi esterification is the chemical reaction of an aliphatic carboxylic acid and 2,4,6-trichlorobenzoyl chloride (TCBC, Yamaguchi reagent) to form a mixed anhydride which, upon reaction with an alcohol in the presence of stoichiometric amount of DMAP, produces the desired ester. It was first reported by Masaru Yamaguchi et al. in 1979 ...
Cetylpyridinium chloride is known to cause tooth staining in approximately 3 percent of users. [14] The Crest brand has noted that this staining is actually an indication that the product is working as intended, as the stains are a result of bacteria dying on the teeth. [15]
The Steglich esterification is a variation of an esterification with dicyclohexylcarbodiimide as a coupling reagent and 4-dimethylaminopyridine as a catalyst.The reaction was first described by Wolfgang Steglich in 1978. [1]
DMAP, as the program is commonly called, works like this: hunters can get permits that allow them to harvest antlerless deer — one per tag — on the specific property or area for which it was ...
However, with the addition of 4-dimethylaminopyridine (DMAP) as a catalyst, the reaction can take place at room temperature. [8] With some acids, this reaction can take place even in the absence of an α-amino group. This reaction should not be confused with the Dakin reaction.