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  2. Sulfur hexafluoride - Wikipedia

    en.wikipedia.org/wiki/Sulfur_hexafluoride

    Sulfur hexafluoride or sulphur hexafluoride (British spelling) is an inorganic compound with the formula SF 6. It is a colorless, odorless, non-flammable, and non-toxic gas. SF 6 has an octahedral geometry, consisting of six fluorine atoms attached to a central sulfur atom. It is a hypervalent molecule. [citation needed] Typical for a nonpolar ...

  3. Octahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Octahedral_molecular_geometry

    When an anionic ligand replaces a coordinated water molecule the reaction is called an anation. The reverse reaction, water replacing an anionic ligand, is called aquation. For example, the [CoCl(NH 3) 5] 2+ slowly yields [Co(NH 3) 5 (H 2 O)] 3+ in water, especially in the presence of acid or base. Addition of concentrated HCl converts the aquo ...

  4. Hypervalent molecule - Wikipedia

    en.wikipedia.org/wiki/Hypervalent_molecule

    Hypervalent iodine compounds are useful reagents in organic chemistry (e.g. Dess–Martin periodinane) Tetra-, penta- and hexavalent phosphorus, silicon, and sulfur compounds (e.g. PCl 5, PF 5, SF 6, sulfuranes and persulfuranes) Noble gas compounds (ex. xenon tetrafluoride, XeF 4) Halogen polyfluorides (ex. chlorine pentafluoride, ClF 5)

  5. Three-center four-electron bond - Wikipedia

    en.wikipedia.org/wiki/Three-center_four-electron...

    3, X = F, Br, Cl, I) via a molecular orbital (MO) description, building on the concept of the "half-bond" introduced by Rundle in 1947. [ 4 ] [ 5 ] In this model, two of the four electrons occupy an all in-phase bonding MO, while the other two occupy a non-bonding MO, leading to an overall bond order of 0.5 between adjacent atoms (see Molecular ...

  6. Hexafluorophosphate - Wikipedia

    en.wikipedia.org/wiki/Hexafluorophosphate

    Hexafluorophosphate is an anion with chemical formula of [PF 6] −.It is an octahedral species that imparts no color to its salts. [PF 6] − is isoelectronic with sulfur hexafluoride, SF 6, and the hexafluorosilicate dianion, [SiF 6] 2−, and hexafluoroantimonate [SbF 6] −.

  7. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths , bond angles , torsional angles and any other geometrical parameters that determine the position of each atom.

  8. Tetrahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Tetrahedral_molecular_geometry

    In the gas phase, a single water molecule has an oxygen atom surrounded by two hydrogens and two lone pairs, and the H 2 O geometry is simply described as bent without considering the nonbonding lone pairs. [citation needed] However, in liquid water or in ice, the lone pairs form hydrogen bonds with neighboring water molecules. The most common ...

  9. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    Shape of water molecule showing that the real bond angle 104.5° deviates from the ideal sp 3 angle of 109.5°. In chemistry, Bent's rule describes and explains the relationship between the orbital hybridization and the electronegativities of substituents. [1] [2] The rule was stated by Henry A. Bent as follows: [2]