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The Haber process, [1] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [ 2 ] [ 3 ] It converts atmospheric nitrogen (N 2 ) to ammonia (NH 3 ) by a reaction with hydrogen (H 2 ) using finely divided iron metal as a catalyst:
Haber's rule states that, for a given poisonous gas, =, where is the concentration of the gas (mass per unit volume), is the amount of time necessary to breathe the gas to produce a given toxic effect, and is a constant, depending on both the gas and the effect. Thus, the rule states that doubling the concentration will halve the time, for example.
Le Chatelier–Braun principle analyzes the qualitative behaviour of a thermodynamic system when a particular one of its externally controlled state variables, say , changes by an amount , the 'driving change', causing a change , the 'response of prime interest', in its conjugate state variable , all other externally controlled state variables remaining constant.
Equilibrium constants are defined in terms of fugacity. If the gases are at sufficiently low pressure that they behave as ideal gases, the equilibrium constant can be defined as a quotient of partial pressures. An example of gas-phase equilibrium is provided by the Haber–Bosch process of ammonia synthesis.
The Haber process, [146] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [ 147 ] [ 148 ] It converts atmospheric nitrogen (N 2 ) to ammonia (NH 3 ) by a reaction with hydrogen (H 2 ) using finely divided iron metal as a catalyst:
Haber's rule is a mathematical statement relating the concentration of a poisonous gas and how long it must be breathed to result in death. Hack's law: a hydrological law relating longest stream length in a basin with the area of the basin. Named after John Tilton Hack.
If a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to partially reverse the change. For example, adding more S (to the chemical reaction above) from the outside will cause an excess of products, and the system will try to counteract this by increasing the reverse reaction and pushing the ...
The history of the Haber process begins with the invention of the Haber process at the dawn of the twentieth century. The process allows the economical fixation of atmospheric dinitrogen in the form of ammonia, which in turn allows for the industrial synthesis of various explosives and nitrogen fertilizers, and is probably the most important industrial process developed during the twentieth ...