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In chemistry, the term chemically inert is used to describe a substance that is not chemically reactive.From a thermodynamic perspective, a substance is inert, or nonlabile, if it is thermodynamically unstable (positive standard Gibbs free energy of formation) yet decomposes at a slow, or negligible rate.
The Boudouard reaction, named after Octave Leopold Boudouard, is the redox reaction of a chemical equilibrium mixture of carbon monoxide and carbon dioxide at a given temperature. It is the disproportionation of carbon monoxide into carbon dioxide and graphite or its reverse: [1] 2CO ⇌ CO 2 + C
It is non-toxic, and belongs to a select group of substances that penetrate the blood–brain barrier, causing mild to full surgical anesthesia when inhaled in high concentrations with oxygen. Xenon has a high ionisation energy (1170.4 kJ/mol), low electron affinity (estimated at −80 kJ/mol), and high electronegativity (2.582 χSpec).
Generally, all noble gases except oganesson (helium, neon, argon, krypton, xenon, and radon), nitrogen, and carbon dioxide are considered inert gases. The term inert gas is context-dependent because several of the inert gases, including nitrogen and carbon dioxide, can be made to react under certain conditions. [1] [2]
Carbon dioxide binds to metals in only a few ways. The bonding mode depends on the electrophilicity and basicity of the metal centre. [ 2 ] Most common is the η 2 -CO 2 coordination mode as illustrated by Aresta's complex, Ni(CO 2 )( PCy 3 ) 2 , which was the first reported complex of CO 2.
The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide: . 2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g). Metals in the middle of the reactivity series, such as iron, will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt, such as iron(II) sulfate:
The Goldschmidt classification, [1] [2] developed by Victor Goldschmidt (1888–1947), is a geochemical classification which groups the chemical elements within the Earth according to their preferred host phases into lithophile (rock-loving), siderophile (iron-loving), chalcophile (sulfide ore-loving or chalcogen-loving), and atmophile (gas-loving) or volatile (the element, or a compound in ...
Xenon is known to function as a metal ligand. In addition to the charged [AuXe 4] 2+, xenon, krypton, and argon all reversibly bind to gaseous M(CO) 5, where M=Cr, Mo, or W. P-block metals also bind noble gases: XeBeO has been observed spectroscopically and both XeBeS and FXeBO are predicted stable. [33]