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The Schoenflies (or Schönflies) notation, named after the German mathematician Arthur Moritz Schoenflies, is a notation primarily used to specify point groups in three dimensions. Because a point group alone is completely adequate to describe the symmetry of a molecule , the notation is often sufficient and commonly used for spectroscopy .
In Schoenflies notation, point groups are denoted by a letter symbol with a subscript. The symbols used in crystallography mean the following: C n (for cyclic) indicates that the group has an n-fold rotation axis.
Coxeter notation offers a bracketed notation equivalent to the Coxeter diagram, with markup symbols for rotational and other subsymmetry point groups. In Schoenflies notation, the reflective point groups in 3D are C nv, D nh, and the full polyhedral groups T, O, and I.
In Schoenflies notation, the symbol of a space group is represented by the symbol of corresponding point group with additional superscript. The superscript doesn't give any additional information about symmetry elements of the space group, but is instead related to the order in which Schoenflies derived the space groups.
John Conway uses a variation of the Schoenflies notation, based on the groups' quaternion algebraic structure, labeled by one or two upper case letters, and whole number subscripts. The group order is defined as the subscript, unless the order is doubled for symbols with a plus or minus, "±", prefix, which implies a central inversion .
Schönflies notation is used, with Coxeter notation in brackets, and orbifold notation in parentheses. The term horizontal (h) is used with respect to a vertical axis of rotation. In 2D, the symmetry group D n includes reflections in lines. When the 2D plane is embedded horizontally in a 3D space, such a reflection can either be viewed as the ...
The following table lists many of the point groups applicable to molecules, labelled using the Schoenflies notation, which is common in chemistry and molecular spectroscopy. The descriptions include common shapes of molecules, which can be explained by the VSEPR model.
Arthur Moritz Schoenflies (German: [ˈʃøːnfliːs]; 17 April 1853 – 27 May 1928), sometimes written as Schönflies, was a German mathematician, known for his contributions to the application of group theory to crystallography, and for work in topology.