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Structure of the chloromethyl group. In organic chemistry, the chloromethyl group is a functional group that has the chemical formula −CH 2 −Cl. The naming of this group is derived from the methyl group (which has the formula −CH 3), by replacing one hydrogen atom by a chlorine atom. Compounds with this group are a subclass of the ...
Chloromethane was a widely used refrigerant, but its use has been discontinued. It was particularly dangerous among the common refrigerants of the 1930s due to its combination of toxicity, flammability and lack of odor as compared with other toxic refrigerants such as sulfur dioxide and ammonia . [ 24 ]
Chlorofluoromethane or Freon 31 is the hydrochlorofluorocarbon (HCFC) with the formula CH 2 ClF. It is a colorless, odorless, flammable gas. [ 1 ] It is a class II ozone depleting substance and in accordance with the montreal protocol, its production and import were banned on 1 January 2015.
c 6 h 5 ch 2 cl + 2 koh + 2 [o] → c 6 h 5 cook + kcl + h 2 o Benzyl chloride may be used in the synthesis of amphetamine-class drugs, and for this reason, sales of benzyl chloride are monitored as a List II drug precursor chemical by the US Drug Enforcement Administration .
PhN=N-N(CH 2) 5 + 2 HF → PhF + N 2 + [(CH 2) 5 NH 2]F. Historical note: in Wallach's era, the element fluorine was symbolized with "Fl". Thus, his procedure is subtitled "Fluorbenzol, C 6 H 5 Fl". [1] On the laboratory scale, PhF is prepared by the thermal decomposition of the benzenediazonium tetrafluoroborate: PhN 2 BF 4 → PhF + BF 3 + N 2
Chloroformates are used as reagents in organic chemistry. For example, benzyl chloroformate is used to introduce the Cbz (carboxybenzyl) protecting group and fluorenylmethyloxycarbonyl chloride is used to introduce the FMOC protecting group. Chloroformates are popular in the field of chromatography as derivatization agents.
Electrophilic fluorinating reagents could in principle operate by electron transfer pathways or an S N 2 attack at fluorine. This distinction has not been decided. [2] By using a charge-spin separated probe, [3] it was possible to show that the electrophilic fluorination of stilbenes with Selectfluor proceeds through an SET/fluorine atom transfer mechanism.
Chloroethyl chloroformates (chemical formula: C 3 H 4 Cl 2 O 2) are a pair of related chemical compounds. They can be used to form protecting groups and as N-dealkylating agents. They can be used to form protecting groups and as N-dealkylating agents.