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Methyl tert-butyl ether (MTBE), also known as tert-butyl methyl ether, is an organic compound with a structural formula (CH 3) 3 COCH 3. MTBE is a volatile, flammable, and colorless liquid that is sparingly soluble in water. [ 1 ]
The MTBE controversy concerns methyl tert-butyl ether (MTBE), a gasoline additive that replaced tetraethyllead.MTBE is an oxygenate and raises gasoline's octane number.Its use declined in the United States in response to environmental and health concerns.
Methyl tert-butyl ether (MTBE), now outlawed in many states of the U.S. for road use because of water contamination. Tertiary amyl methyl ether (TAME) Tertiary hexyl methyl ether (THEME) Ethyl tertiary butyl ether (ETBE) Tertiary amyl ethyl ether (TAEE) Diisopropyl ether (DIPE) Antioxidants, stabilizers Butylated hydroxyanisole (BHA) Butylated ...
This is known as oxygenated fuel and often (but not entirely correctly, as there are reformulated gasolines without oxygenate) as reformulated gasoline. Methyl tert-butyl ether (MTBE) was the most common fuel additive in the United States, prior to government mandated use of ethanol. Typically, gasoline with added MTBE is called reformulated ...
tert-Butyl alcohol is used as a solvent, ethanol denaturant, paint remover ingredient, and gasoline octane booster and oxygenate.It is a chemical intermediate used to produce methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by reaction with methanol and ethanol, respectively, and tert-butyl hydroperoxide (TBHP) by reaction with hydrogen peroxide.
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
In chemistry, alkyl is a group, a substituent, that is attached to other molecular fragments. For example, alkyl lithium reagents have the empirical formula Li(alkyl), where alkyl = methyl, ethyl, etc. A dialkyl ether is an ether with two alkyl groups, e.g., diethyl ether O(CH 2 CH 3) 2.
In the example, the oxygen atom in methyl tert-butyl ether is reversibly protonated. The resulting oxonium ion then decomposes into methanol and a relatively stable tert-butyl cation. The latter is then attacked by a nucleophile halide (here bromide), yielding tert-butyl bromide.
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