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[12] [13] Copper(II) chloride reacts with several metals to produce copper metal or copper(I) chloride (CuCl) with oxidation of the other metal. To convert copper(II) chloride to copper(I) chloride, it can be convenient to reduce an aqueous solution with sulfur dioxide as the reductant: [8] 2 CuCl 2 + SO 2 + 2 H 2 O → 2 CuCl + 2 HCl + H 2 SO 4
Simplified diagram of the Copper–Chlorine cycle. The copper–chlorine cycle (Cu–Cl cycle) is a four-step thermochemical cycle for the production of hydrogen. The Cu–Cl cycle is a hybrid process that employs both thermochemical and electrolysis steps. It has a maximum temperature requirement of about 530 degrees Celsius. [1]
The main use of copper(I) chloride is as a precursor to the fungicide copper oxychloride. For this purpose aqueous copper(I) chloride is generated by comproportionation and then air-oxidized: [12] Cu + CuCl 2 → 2 CuCl 4 CuCl + O 2 + 2 H 2 O → Cu 3 Cl 2 (OH) 4 + CuCl 2. Copper(I) chloride catalyzes a variety of organic reactions, as
9.3.1 Electrolysis of a solution of sodium chloride. ... metals when there is a temperature ... in solution, and copper ions accept electrons from the copper metal ...
For the electrolysis of aqueous copper(II) sulfate (CuSO 4) as an example, with Cu 2+ (aq) and SO 2− 4 (aq) ions, the cathode reaction is the reduction Cu 2+ (aq) + 2 e − → Cu(s) and the anode reaction is the corresponding oxidation of Cu to Cu 2+.
For the electrolysis of a neutral (pH 7) sodium chloride solution, the reduction of sodium ion is thermodynamically very difficult and water is reduced evolving hydrogen leaving hydroxide ions in solution.
Chlorine can be manufactured by the electrolysis of a sodium chloride solution (), which is known as the Chloralkali process.The production of chlorine results in the co-products caustic soda (sodium hydroxide, NaOH) and hydrogen gas (H 2).
Acid copper sulfate electrolytes are relatively simple solutions of copper sulfate and sulfuric acid that are cheaper and easier to maintain and control than cyanide copper electrolytes. [2] Compared to cyanide baths, they provide higher current efficiency and allow for higher current density and thus faster plating rates, but they usually have ...