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Extinction coefficient refers to several different measures of the absorption of light in a medium: Attenuation coefficient , sometimes called "extinction coefficient" in meteorology or climatology Mass extinction coefficient , how strongly a substance absorbs light at a given wavelength, per mass density
A. R. Forouhi and I. Bloomer deduced dispersion equations for the refractive index, n, and extinction coefficient, k, which were published in 1986 [1] and 1988. [2] The 1986 publication relates to amorphous materials, while the 1988 publication relates to crystalline.
The SI unit of molar absorption coefficient is the square metre per mole (m 2 /mol), but in practice, quantities are usually expressed in terms of M −1 ⋅cm −1 or L⋅mol −1 ⋅cm −1 (the latter two units are both equal to 0.1 m 2 /mol).
The absorption coefficient of a volume, denoted μ a, and the scattering coefficient of a volume, denoted μ s, are defined the same way as the attenuation coefficient. [ 6 ] The attenuation coefficient of a volume is the sum of absorption coefficient and scattering coefficients: [ 6 ]
Here, the real part n is the refractive index and indicates the phase velocity, while the imaginary part κ is called the extinction coefficient [39]: 36 indicates the amount of attenuation when the electromagnetic wave propagates through the material.
Once a reference signal is acquired, it is compared to the transmitted light Is of the measured sample. In order to calculate the associated extinction coefficient μ t, Beer's law can be applied as follows: I s = I o exp(-μ t d), where d is the sample thickness. The extinction coefficient is therefore: μ t = -ln(I s /I o)/d.
Thus a scattering coefficient μ s and an absorption coefficient μ a can be combined into a total extinction coefficient μ = μ s + μ a. [ 6 ] Importantly, Beer also seems to have conceptualized his result in terms of a given thickness' opacity, writing "If λ is the coefficient (fraction) of diminution, then this coefficient (fraction) will ...
absorption coefficient is essentially (but not quite always) synonymous with attenuation coefficient; see attenuation coefficient for details; molar absorption coefficient or molar extinction coefficient , also called molar absorptivity , is the attenuation coefficient divided by molarity (and usually multiplied by ln(10), i.e., decadic); see ...