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Other reactants can be present, but their concentration has no effect on the rate. The rate law for a first order reaction is [] = [], The unit of k is s-1. [18] Although not affecting the above math, the majority of first order reactions proceed via intermolecular collisions.
Chemical reactions: The rates of certain types of chemical reactions depend on the concentration of one or another reactant. Reactions whose rate depends only on the concentration of one reactant (known as first-order reactions) consequently follow exponential decay. For instance, many enzyme-catalyzed reactions behave this way.
First-order logic, a formal logical system used in mathematics, philosophy, linguistics, and computer science; First-order predicate, a predicate that takes only individual(s) constants or variables as argument(s) First-order predicate calculus; First-order theorem provers; First-order theory; Monadic first-order logic
For a first-order reaction, it has units of s −1. For that reason, it is often called frequency factor . According to collision theory , the frequency factor, A, depends on how often molecules collide when all concentrations are 1 mol/L and on whether the molecules are properly oriented when they collide.
[A] can provide intuitive insight about the order of each of the reagents. If plots of v / [A] vs. [B] overlay for multiple experiments with different-excess, the data are consistent with a first-order dependence on [A]. The same could be said for a plot of v / [B] vs. [A]; overlay is consistent with a first-order dependence on [B].
Generally, as the temperature increases so does the rate at which the reaction occurs. Residence time, , is the average amount of time a discrete quantity of reagent spends inside the tank. Assume: isothermal conditions, or constant temperature (k is constant) single, irreversible reaction (ν A = -1) first-order reaction (r = k C A)
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Iron rusting has a low reaction rate. This process is slow. Wood combustion has a high reaction rate. This process is fast. The reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. [1]