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tert-Butyl alcohol is used as a solvent, ethanol denaturant, paint remover ingredient, and gasoline octane booster and oxygenate.It is a chemical intermediate used to produce methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by reaction with methanol and ethanol, respectively, and tert-butyl hydroperoxide (TBHP) by reaction with hydrogen peroxide.
IUPAC name IARC carcinogen group Toxic metabolite(s) Alcohol by volume (ABV) [1] LD50 in rat, oral [2]; Ethanol: Group 1: Acetaldehyde → acetic acid Up to 95.6% in rectified spirit
Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C 4 H 9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; [1] all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, sec-BuOH, i-BuOH, and t-BuOH).
Butyl acrylate is of low acute toxicity with an LD 50 (rat) of 3143 mg/kg. [4]In rodent models, butyl acrylate is metabolized by carboxylesterase or reactions with glutathione; this detoxification produces acrylic acid, butanol, and mercapturic acid waste, which are excreted.
Tertiary alcohols react with strong acids to generate carbocations. The reaction is related to their dehydration, e.g. isobutylene from tert-butyl alcohol. A special kind of dehydration reaction involves triphenylmethanol and especially its amine-substituted derivatives. When treated with acid, these alcohols lose water to give stable ...
The acute toxicity of 1-butanol is relatively low, with oral LD 50 values of 790–4,360 mg/kg (rat; comparable values for ethanol are 7,000–15,000 mg/kg). [ 8 ] [ 32 ] [ 11 ] It is metabolized completely in vertebrates in a manner similar to ethanol : alcohol dehydrogenase converts 1-butanol to butyraldehyde ; this is then converted to ...
4-tert-Butyl-2,6,7-trioxa-1 ... It is the most toxic bicyclic phosphate known, with an LD 50 of 36 μg/kg in mice. [2] Some sources claim that TBPO is as toxic as VX. [3]
1 US gallon or 3.785 litres of denatured alcohol in a metal container. Denatured alcohol, also known as methylated spirits, metho, or meths in Australia, Ireland, New Zealand, South Africa, and the United Kingdom, and as denatured rectified spirit, is ethanol that has additives to make it poisonous, bad-tasting, foul-smelling, or nauseating to discourage its recreational consumption.