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Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
The diffusion equation is a parabolic partial differential equation.In physics, it describes the macroscopic behavior of many micro-particles in Brownian motion, resulting from the random movements and collisions of the particles (see Fick's laws of diffusion).
Fick's laws of diffusion describe diffusion, and define the diffusion coefficient D. Derived by Adolf Fick in 1855. Finagle's law: "Anything that can go wrong, will—at the worst possible moment." or "The perversity of the Universe tends towards a maximum."
Bottom: With an enormous number of solute molecules, all randomness is gone: The solute appears to move smoothly and systematically from high-concentration areas to low-concentration areas, following Fick's laws. Molecular diffusion, often simply called diffusion, is the thermal motion of all (liquid or gas) particles at temperatures above ...
According to Fick's laws, the diffusion flux is proportional to the negative gradient of concentrations. It goes from regions of higher concentration to regions of lower concentration. Sometime later, various generalizations of Fick's laws were developed in the frame of thermodynamics and non-equilibrium thermodynamics. [4]
In chemical physics, atomic diffusion is a diffusion process whereby the random, thermally-activated movement of atoms in a solid results in the net transport of atoms. For example, helium atoms inside a balloon can diffuse through the wall of the balloon and escape, resulting in the balloon slowly deflating.
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The Boltzmann–Matano method is used to convert the partial differential equation resulting from Fick's law of diffusion into a more easily solved ordinary differential equation, which can then be applied to calculate the diffusion coefficient as a function of concentration.