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The circuit topology of a folded linear polymer refers to the arrangement of its intra-molecular contacts. Examples of linear polymers with intra-molecular contacts are nucleic acids and proteins . Proteins fold via the formation of contacts of various natures, including hydrogen bonds, disulfide bonds, and beta-beta interactions. [ 1 ]
A series circuit with a voltage source (such as a battery, or in this case a cell) and three resistance units. Two-terminal components and electrical networks can be connected in series or parallel. The resulting electrical network will have two terminals, and itself can participate in a series or parallel topology.
Consequently, hydrogen bonds between or within solute molecules dissolved in water are almost always unfavorable relative to hydrogen bonds between water and the donors and acceptors for hydrogen bonds on those solutes. [44] Hydrogen bonds between water molecules have an average lifetime of 10 −11 seconds, or 10 picoseconds. [45]
Protons tunnel across a series of hydrogen bonds between hydronium ions and water molecules.. The Grotthuss mechanism (also known as proton jumping) is a model for the process by which an 'excess' proton or proton defect diffuses through the hydrogen bond network of water molecules or other hydrogen-bonded liquids through the formation and concomitant cleavage of covalent bonds involving ...
In these, the CO group of residue i is hydrogen-bonded to the NH of residue i+6, and the CO group of residue i+1 is hydrogen-bonded to the NH of residue i+5. Rare “left-handed” six-residue Schellman loops occur; these have the same hydrogen bonds, but residues i +1, i +2, and i +3 have positive φ values while the φ value of residue i +4 ...
In one sort, the beta bulge loop, one of the hydrogen bonds of the beta-bulge also forms a beta turn or alpha turn, such that the motif is often at the loop of a beta hairpin. [5] In the other sort, the beta link, the beta bulge occurs in combination with, and overlaps, a type II beta turn.
For example, residue i may form hydrogen bonds to residues j − 1 and j + 1; this is known as a wide pair of hydrogen bonds. By contrast, residue j may hydrogen-bond to different residues altogether, or to none at all. The hydrogen bond arrangement in parallel beta sheet resembles that in an amide ring motif with 11 atoms.
Bond strength is less than 1 kcal/mol. In the case of aromatic C–H donors, C–H···O interactions are not linear due to influence of aromatic ring substituents near the interacting C-H group. [ 6 ] [ 7 ] If aromatic molecules involved in С–Н···О interaction belong to the group of polycyclic aromatic hydrocarbons , the strength of C ...