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Boric acid is a weak acid, with pK a (the pH at which buffering is strongest because the free acid and borate ion are in equal concentrations) of 9.24 in pure water at 25 °C. But apparent p K a is substantially lower in swimming pool or ocean waters because of interactions with various other molecules in solution.
Excess boron is toxic to plants so care must be taken to ensure correct application rate and even coverage. [7] While boron may be sprayed on leaves, excess will cause plant damage. Application of boron may not correct boron deficiency in alkaline soils because even with the addition of boron, it may remain unavailable for plant absorption.
Borate anions are largely in the form of the undissociated acid in aqueous solution at physiological pH. No further metabolism occurs in either animals or plants. In animals, boric acid/borate salts are essentially completely absorbed following oral ingestion. Absorption occurs via inhalation, although quantitative data are unavailable.
Boric acid is only marginally more toxic to most lifeforms than normal table salt, with exposure in humans and other mammals widely regarded as being safe. Its use as an insecticide in malarial control (instead of compounds which demonstrate high levels of mammalian toxicity or carcinogenicity) is thus seen as advantageous. [1] [2] [4]
They are obtained through the soil as phosphates, boric acid, and silicic acid, respectively. Other nutrients used by plants are potassium, sodium, calcium, magnesium, manganese, chlorine, iron, copper, zinc, and molybdenum. [49] Plants uptake essential elements from the soil through their roots and from the air (consisting of mainly nitrogen ...
It is a sodium salt of the orthoboric acid B(OH) 3. The compound is also called trisodium orthoborate, sodium orthoborate, or just sodium borate. However, "sodium orthoborate" has been used also for a compound with formula Na 4 B 2 O 5, which would correspond to an equimolar mixture of sodium metaborate NaBO 2 and trisodium borate proper.
This page provides supplementary chemical data on boric acid. Thermodynamic properties. Phase behavior Triple point? K (? °C), ? Pa Critical point? K (? °C), ?
Borax is also easily converted to boric acid and other borates, which have many applications. Its reaction with hydrochloric acid to form boric acid is: Na 2 B 4 O 7 ·10H 2 O + 2 HCl → 4 H 3 BO 3 + 2 NaCl + 5 H 2 O. Borax is sufficiently stable to find use as a primary standard for acid-base titrimetry. [17]: p.316
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