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  2. Butyl group - Wikipedia

    en.wikipedia.org/wiki/Butyl_group

    The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.

  3. Rotamer - Wikipedia

    en.wikipedia.org/wiki/Rotamer

    The repulsion between an axial t-butyl group and hydrogen atoms in the 1,3-diaxial position is so strong that the cyclohexane ring will revert to a twisted boat conformation. The strain in cyclic structures is usually characterized by deviations from ideal bond angles ( Baeyer strain ), ideal torsional angles ( Pitzer strain ) or transannular ...

  4. Newman projection - Wikipedia

    en.wikipedia.org/wiki/Newman_projection

    A Newman projection is a drawing that helps visualize the 3-dimensional structure of a molecule. [1] This projection most commonly sights down a carbon-carbon bond, making it a very useful way to visualize the stereochemistry of alkanes.

  5. Rotamers - Wikipedia

    en.wikipedia.org/wiki/Gauche_conformation

    The repulsion between an axial t-butyl group and hydrogen atoms in the 1,3-diaxial position is so strong that the cyclohexane ring will revert to a twisted boat conformation. The strain in cyclic structures is usually characterized by deviations from ideal bond angles ( Baeyer strain ), ideal torsional angles ( Pitzer strain ) or transannular ...

  6. 1,3,5-Tris(4-(tert-butyl)-3-hydroxy-2,6-dimethylbenzyl)-1,3,5 ...

    en.wikipedia.org/wiki/1,3,5-Tris(4-(tert-butyl...

    As each phenol group contains only a single t-butyl group they are considered to have low steric hindrance and thus high activity. Arranging three of these around an isocyanurate core gives a compound with a sufficiently high boiling point that it is not volatilised out of the plastic during plastic extrusion and moulding (up to 320 °C in the case of PA).

  7. File:Sec-butyl group.svg - Wikipedia

    en.wikipedia.org/wiki/File:Sec-butyl_group.svg

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  8. Butanol - Wikipedia

    en.wikipedia.org/wiki/Butanol

    Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C 4 H 9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; [1] all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, sec-BuOH, i-BuOH, and t-BuOH).

  9. 1-Bromobutane - Wikipedia

    en.wikipedia.org/wiki/1-Bromobutane

    Such reagents are used to attach butyl groups to various substrates. 1-Bromobutane is the precursor to n-butyllithium: [4] 2 Li + C 4 H 9 X → C 4 H 9 Li + LiX where X = Cl, Br. The lithium for this reaction contains 1-3% sodium.