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An oxide (/ ˈ ɒ k s aɪ d /) is a chemical compound containing at least one oxygen atom and one other element [1] in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of –2) of oxygen, an O 2– ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials ...
The charge on the ion is +5 − 3 × 2 = −1, and so the formula is ClO − 3. The structure of the ion is predicted by VSEPR theory to be pyramidal, with three bonding electron pairs and one lone pair. In a similar way, The oxyanion of chlorine(III) has the formula ClO − 2, and is bent with two lone pairs and two bonding pairs.
As an example, summing bond orders in the ammonium cation yields −4 at the nitrogen of formal charge +1, with the two numbers adding to the oxidation state of −3: The sum of oxidation states in the ion equals its charge (as it equals zero for a neutral molecule). Also in anions, the formal (ionic) charges have to be considered when nonzero.
The formal charge of any atom in a molecule can be calculated by the following equation: = where V is the number of valence electrons of the neutral atom in isolation (in its ground state); L is the number of non-bonding valence electrons assigned to this atom in the Lewis structure of the molecule; and B is the total number of electrons shared ...
A sesquioxide is an oxide of an element (or radical), where the ratio between the number of atoms of that element and the number of atoms of oxygen is 2:3. For example, aluminium oxide Al 2 O 3 and phosphorus(III) oxide P 4 O 6 are sesquioxides.
In these cases the oxidation number (the same as the charge) of the metal ion is represented by a Roman numeral in parentheses immediately following the metal ion name. For example, in uranium(VI) fluoride the oxidation number of uranium is 6. Another example is the iron oxides. FeO is iron(II) oxide and Fe 2 O 3 is iron(III) oxide.
Osmium dioxide is another known oxide of osmium, which can be obtained by the reaction of osmium with a variety of oxidizing agents, including, sodium chlorate, osmium tetroxide, and nitric oxide at about 600 °C. [18] [19] It does not dissolve in water, but is attacked by dilute hydrochloric acid. [20] [21] The crystals have rutile structure. [22]
Rubidium superoxide or rubidium hyperoxide is a chemical compound with the chemical formula RbO 2. In terms of oxidation states, the negatively charged superoxide and positively charged rubidium give it a structural formula of Rb + [O 2] −. [2]
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