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  2. 1-Bromohexane - Wikipedia

    en.wikipedia.org/wiki/1-Bromohexane

    Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative. [2] 1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. [3]

  3. Dehydrohalogenation - Wikipedia

    en.wikipedia.org/wiki/Dehydrohalogenation

    The resulting HCl can be reused in oxychlorination reaction. Thermally induced dehydrofluorinations are employed in the production of fluoroolefins and hydrofluoroolefins. One example is the preparation of 1,2,3,3,3-pentafluoropropene from 1,1,2,3,3,3-hexafluoropropane: CF 2 HCH(F)CF 3 → CHF=C(F)CF 3 + HF

  4. Gomberg–Bachmann reaction - Wikipedia

    en.wikipedia.org/wiki/Gomberg–Bachmann_reaction

    The Gomberg–Bachmann reaction, named for the Russian-American chemist Moses Gomberg and the American chemist Werner Emmanuel Bachmann, is an aryl-aryl coupling reaction via a diazonium salt. [1] [2] [3] The arene compound (here benzene) is reacted with a diazonium salt in the presence of a base to provide the biaryl through an intermediate ...

  5. Persistent carbene - Wikipedia

    en.wikipedia.org/wiki/Persistent_carbene

    Reaction of imidazol-2-ylidenes with 1-bromohexane gave 90% of the 2-substituted adduct, with only 10% of the corresponding alkene, indicating that these molecules are also reasonably nucleophilic. p K a values for the conjugate acids of several NHC families have been examined in aqueous solution. pKa values of triazolium ions lie in the range ...

  6. 1-Bromobutane - Wikipedia

    en.wikipedia.org/wiki/1-Bromobutane

    1-Bromobutane is the precursor to n-butyllithium: [4] 2 Li + C 4 H 9 X → C 4 H 9 Li + LiX where X = Cl, Br. The lithium for this reaction contains 1-3% sodium. When bromobutane is the precursor, the product is a homogeneous solution, consisting of a mixed cluster containing both LiBr and LiBu.

  7. Substitution reaction - Wikipedia

    en.wikipedia.org/wiki/Substitution_reaction

    The two reactions are named according tho their rate law, with S N 1 having a first-order rate law, and S N 2 having a second-order. [2] S N 1 reaction mechanism occurring through two steps. The S N 1 mechanism has two steps. In the first step, the leaving group departs, forming a carbocation (C +). In the second step, the nucleophilic reagent ...

  8. 37 Things You Should Stop Paying for ASAP - AOL

    www.aol.com/finance/37-things-stop-paying-asap...

    Baby Food. Homemade baby food is far cheaper than commercial baby food — and you know exactly what's in it. You don't need a gadget designed specifically for making baby food.Just boil or steam ...

  9. SN1 reaction - Wikipedia

    en.wikipedia.org/wiki/SN1_reaction

    An example of a reaction proceeding in a S N 1 fashion is the synthesis of 2,5-dichloro-2,5-dimethylhexane from the corresponding diol with concentrated hydrochloric acid: [8] As the alpha and beta substitutions increase with respect to leaving groups, the reaction is diverted from S N 2 to S N 1.