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Coupling reactions are a class of metal-catalyzed reactions involving an organometallic compound RM and an organic halide R′X that together react to form a compound of the type R-R′ with formation of a new carbon–carbon bond. Examples include the Heck reaction, Ullmann reaction, and Wurtz–Fittig reaction. Many variations exist. [3]
The terminology is typically applied to organometallic and coordination complexes, but resembles the Sn2 mechanism in organic chemistry. The opposite pathway is dissociative substitution, being analogous to the Sn1 pathway. Intermediate pathways exist between the pure associative and pure dissociative pathways, these are called interchange ...
A metal detector is an instrument that detects the nearby presence of metal. Metal detectors are useful for finding metal objects on the surface, underground, and under water. A metal detector consists of a control box, an adjustable shaft, and a variable-shaped pickup coil.
The reactions involving charged transition metal complexes (cationic or anionic) are dramatically influenced by solvation, especially in the polar media. As high as 30-50 kcal/mol changes in the potential energy surface (activation energies and relative stability) were calculated if the charge of the metal species was changed during the ...
Competition experiment between SN2 and E2. With ethyl bromide, the reaction product is predominantly the substitution product. As steric hindrance around the electrophilic center increases, as with isobutyl bromide, substitution is disfavored and elimination is the predominant reaction. Other factors favoring elimination are the strength of the ...
General reaction scheme for the S N 1 reaction. The leaving group is denoted "X", and the nucleophile is denoted "Nu–H". The unimolecular nucleophilic substitution (S N 1) reaction is a substitution reaction in organic chemistry.
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