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Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu(NO 3) 2 (H 2 O) x. The hydrates are hygroscopic blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 °C. [5] [6] Common hydrates are the hemipentahydrate and trihydrate.
Thus copper(II) nitrate readily dissociates in aqueous solution to give the aqua complex: Cu(NO 3) 2 + 6 H 2 O → [Cu(H 2 O) 6](NO 3) 2. Pyrolysis of metal nitrates yields oxides. [18] Ni(NO 3) 2 → NiO + NO 2 + 0.5 O 2. This reaction is used to impregnate oxide supports with nickel oxides. Nitrate reductase enzymes convert nitrate to
Copper(II) sulfate is an inorganic compound with the chemical formula Cu SO 4. It forms hydrates CuSO 4 · n H 2 O , where n can range from 1 to 7. The pentahydrate ( n = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate, [ 10 ] while its anhydrous form is white. [ 11 ]
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Crystals of hydrated copper(II) sulfate consist of [Cu(H 2 O) 4] 2+ centers linked to SO 2− 4 ions. Copper is surrounded by six oxygen atoms, provided by two different sulfate groups and four molecules of water. A fifth water resides elsewhere in the framework but does not bind directly to copper. [6]
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Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide. It can be classified as a coordination polymer or a salt. It consists of copper(II) bonded to carbonate and hydroxide with formula Cu 2 (CO 3)(OH) 2. It is a green solid that occurs in nature as the mineral malachite.
The nitrate salt of the acetonitrile complex, i.e., [Cu(MeCN) 4]NO 3, is generated by the reaction of silver nitrate with a suspension of copper metal in acetonitrile. [2] Cu + AgNO 3 + 4 CH 3 CN → [Cu(CH 3 CN) 4]NO 3 + Ag. Tertiary phosphine complexes of the type [Cu(P(C 6 H 5) 3) 3]NO 3 are prepared by the reduction of copper(II) nitrate by ...