Search results
Results from the WOW.Com Content Network
The reagent is an alkaline solution of potassium permanganate. Reaction with double or triple bonds (R 2 C=CR 2 or R−C≡C−R) causes the color to fade from purplish-pink to brown. Aldehydes and formic acid (and formates) also give a positive test. [43] The test is antiquated. Baeyer's reagent reaction
potassium permanganate has a molar mass of 158.034(1) g mol −1, and reacts with five moles of electrons per mole of potassium permanganate, so its equivalent weight is 158.034(1) g mol −1 /5 eq mol −1 = 31.6068(3) g eq −1. Historically, the equivalent weights of the elements were often determined by studying their reactions with oxygen.
For instance, potassium permanganate decomposes at 230 °C to potassium manganate and manganese dioxide, releasing oxygen gas: 2 KMnO 4 → K 2 MnO 4 + MnO 2 + O 2 A permanganate can oxidize an amine to a nitro compound , [ 7 ] [ 8 ] an alcohol to a ketone , [ 9 ] an aldehyde to a carboxylic acid , [ 10 ] [ 11 ] a terminal alkene to a ...
Potassium permanganate will decompose into potassium manganate, manganese dioxide and oxygen gas: 2 KMnO 4 → K 2 MnO 4 + MnO 2 + O 2. This reaction is a laboratory method to prepare oxygen, but produces samples of potassium manganate contaminated with MnO 2. The former is soluble and the latter is not.
An equivalent (symbol: officially equiv; [1] unofficially but often Eq [2]) is the amount of a substance that reacts with (or is equivalent to) an arbitrary amount (typically one mole) of another substance in a given chemical reaction. It is an archaic quantity that was used in chemistry and the biological sciences (see Equivalent weight § In ...
Sodium permanganate is the inorganic compound with the formula Na MnO 4.It is closely related to the more commonly encountered potassium permanganate, but it is generally less desirable, because it is more expensive to produce.
Depending on the conditions in which the titration is performed, the manganese is reduced from an oxidation of +7 to +2, +4, or +6. In most cases, permanganometry is performed in a very acidic solution in which the following electrochemical reaction occurs: [3]
Molar mass: 368.35 g/mol (anhydrous) ... is used to determine the concentration of potassium permanganate, a compound often used in titrations based on redox reactions.