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[citation needed] The term macrocycle is used when a ring-containing compound has a ring of 12 or more atoms. [6] [7] The term polycyclic is used when more than one ring appears in a single molecule. Naphthalene is formally a polycyclic compound, but is more specifically named as a bicyclic compound. Several examples of macrocyclic and ...
An example of a spirocyclic compound is the photochromic switch spiropyran. In fused/condensed [ 5 ] bicyclic compounds , two rings share two adjacent atoms. In other words, the rings share one covalent bond, i.e. the bridgehead atoms are directly connected ( e.g. α-thujene and decalin ).
In the example below, alkylation of 2-methylcyclooctanone occurred to yield the predominantly trans product. Proceeding from the lowest energy conformation of 2-methylcycloctanone, peripheral attack is observed from either one of the low energy (energetic difference of 0.5 (kcal/mol)) enolate conformations, resulting in a trans product from ...
An overview of the different components included in the field of chemical biology. Chemical biology is a scientific discipline between the fields of chemistry and biology.The discipline involves the application of chemical techniques, analysis, and often small molecules produced through synthetic chemistry, to the study and manipulation of biological systems. [1]
Spiro compounds are often prepared by diverse rearrangement reactions. For example, the pinacol-pinacolone rearrangement is illustrated below. [3]: 985 is employed in the preparation of aspiro[4.5]decane. [12]]. The synthesis of a spiro-keto compound form a symmetrical diol
Heterocyclic organic chemistry is the branch of organic chemistry dealing with the synthesis, properties, and applications of organic heterocycles. [2] Examples of heterocyclic compounds include all of the nucleic acids, the majority of drugs, most biomass (cellulose and related materials), and many natural and synthetic dyes. More than half of ...
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In chemistry, catenation is the bonding of atoms of the same element into a series, called a chain. [1] A chain or a ring may be open if its ends are not bonded to each other (an open-chain compound), or closed if they are bonded in a ring (a cyclic compound). The words to catenate and catenation reflect the Latin root catena, "chain".