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The bonding in carbon dioxide (CO 2): all atoms are surrounded by 8 electrons, fulfilling the octet rule. The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas.
In the alkali metals, the outermost electron only feels a net charge of +1, as some of the nuclear charge (which is equal to the atomic number) is cancelled by the inner electrons; the number of inner electrons of an alkali metal is always one less than the nuclear charge. Therefore, the only factor which affects the atomic radius of the alkali ...
Atoms that lose electrons make positively charged ions (called cations). This transfer of electrons is known as electrovalence in contrast to covalence. In the simplest case, the cation is a metal atom and the anion is a nonmetal atom, but these ions can be more complex, e.g. molecular ions like NH + 4 or SO 2− 4.
It is two electrons short of a full octet and readily takes electrons from other elements. It reacts violently with alkali metals and white phosphorus at room temperature and less violently with alkali earth metals heavier than magnesium. At higher temperatures it burns most other metals and many non-metals (including hydrogen, carbon, and sulfur).
It now has 8 total valence electrons, which obeys the octet rule. CH 4, for the central C; neutral counting: C contributes 4 electrons, each H radical contributes one each: 4 + 4 × 1 = 8 valence electrons ionic counting: C 4− contributes 8 electrons, each proton contributes 0 each: 8 + 4 × 0 = 8 electrons. Similar for H:
Consider the sulfate anion (SO 2− 4) with 32 valence electrons; 24 from oxygens, 6 from sulfur, 2 of the anion charge obtained from the implied cation. The bond orders to the terminal oxygens do not affect the oxidation state so long as the oxygens have octets. Already the skeletal structure, top left, yields the correct oxidation states, as ...
Cs > K > Na > Li > alkaline earth metals, i.e., alkali metals > alkaline earth metals, the same as the reverse order of the (gas-phase) ionization energies. This is borne out by the extraction of metallic lithium by the electrolysis of a eutectic mixture of lithium chloride and potassium chloride: lithium metal is formed at the cathode, not ...
The apparent paradox arises when electrons are removed from the transition metal atoms to form ions. The first electrons to be ionized come not from the 3d-orbital, as one would expect if it were "higher in energy", but from the 4s-orbital. This interchange of electrons between 4s and 3d is found for all atoms of the first series of transition ...