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Magnesium carbonate, Mg CO 3 (archaic name magnesia alba), is an inorganic salt that is a colourless or white solid. Several hydrated and basic forms of magnesium carbonate also exist as minerals .
It represents the pentahydrate of magnesium carbonate, and has the total formula MgCO 3 ·5H 2 O . [2] Landsfordite was discovered in 1888 in a coal mine in Lansford, Pennsylvania . It crystallizes in the monoclinic system (space group P2 1 /c [ 3 ] ) and typically occurs as colorless to white prismatic crystals and stalactitic masses. [ 4 ]
Magnesium hypochlorite and magnesium chlorite are unstable compounds, they are easy to hydrolyze, the former generates basic salt Mg(OCl) 2 ·2Mg(OH) 2 and the latter generates hydroxide Mg(OH) 2; magnesium chlorate can be obtained by reacting magnesium carbonate with chloric acid and crystallizing hexahydrate from solution, which can also be ...
It is the most common cave carbonate after calcite and aragonite. [2] The mineral thermally decomposes, [5] [6] over a temperature range of approximately 220 °C to 550 °C, releasing water and carbon dioxide leaving a magnesium oxide residue. Hydromagnesite was first described in 1836 for an occurrence in Hoboken, New Jersey. [3]
Magnesite can also be formed via the carbonation of magnesium serpentine (lizardite) via the following reaction: 2 Mg 3 Si 2 O 5 (OH) 4 + 3 CO 2 → Mg 3 Si 4 O 10 (OH) 2 + 3 MgCO 3 + 3 H 2 O. However, when performing this reaction in the laboratory, the trihydrated form of magnesium carbonate (nesquehonite) will form at room temperature. [6]
In the first publications on mesoporous magnesium carbonate, the material was given the name Upsalite as a reference to Uppsala University and the city of Uppsala, using the Latin spelling with one p. Today, Upsalite is a registered trademark, and in general the material class is designated as mesoporous magnesium carbonates.
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Carnallite's chemical formula is K Mg Cl 3 ·6(H 2 O). Synthetic carnallite crystal specimens can be produced from 1.5 mole percent KCl and 98.5 mole percent MgCl 2 ·6H 2 O by slow crystallization at 25 °C. [8] Its density is 1.602 g/cm 3. [8] Carnallite can also be produced by grinding the combination of hydrated magnesium chloride and ...