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3-Nitrobenzaldehyde is the primary product obtained via the mono-nitration of benzaldehyde with nitric acid. [3] C 6 H 5 CHO + HNO 3 → O 2 NC 6 H 4 CHO + H 2 O. Product distribution is about 19% for the ortho-, 72% for the meta- and 9% for the para isomers.
The nitration of benzaldehyde produces mostly 3-nitrobenzaldehyde.Partly for this reason, 2-nitrobenzaldehyde is prepared by indirect routes. [3] The main routes to nitrobenzaldehyde begin with the nitration of styrene or cinnamic acid followed by the conversions of the resulting 2-nitrostyrene and 2-nitrocinnamic acids, respectively.
4-Nitrobenzaldehyde is an organic compound with the formula O 2 NC 6 H 4 CHO.It is one of three isomers of nitrobenzaldehyde. It contains a nitro group para-substituted to an aldehyde.
Benzaldehyde (C 6 H 5 CHO) is an organic compound consisting of a benzene ring with a formyl substituent. It is among the simplest aromatic aldehydes and one of the most industrially useful. It is a colorless liquid with a characteristic almond -like odor , and is commonly used in cherry -flavored sodas . [ 5 ]
It also can be prepared by treating benzaldehyde under nitration conditions, a process that initially converts the aldehyde to the acid. 4-Nitrobenzoic acid is a precursor to 4-aminobenzoic acid , which is in turn used to prepare the anesthetic procaine . 4-Nitrobenzoic acid is prepared by oxidation of 4-nitrotoluene .
β-Nitrostyrene is a chemical precursor for slimicides and dyes. Specifically bromo-nitrostyrene is obtained upon treatment with bromine followed by partial dehydrohalogenation [2] while 2-nitrobenzaldehyde is obtained by treatment with ozone respectively.
The figure below illustrates one of the commonly accepted models for stereoselection without any modification to the Henry reaction. In this model, stereoselectivity is governed by the size of the R groups in the model (such as a carbon chain), as well as by a transition state that minimizes dipole by orienting the nitro group and carbonyl oxygen anti each other (on opposite sides of the ...
The inductive and resonance properties compete with each other but the resonance effect dominates for purposes of directing the sites of reactivity. For nitration, for example, fluorine directs strongly to the para position because the ortho position is inductively deactivated (86% para, 13% ortho, 0.6% meta).