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In chemistry, the Fischer projection, devised by Emil Fischer in 1891, is a two-dimensional representation of a three-dimensional organic molecule by projection. Fischer projections were originally proposed for the depiction of carbohydrates and used by chemists, particularly in organic chemistry and biochemistry. The use of Fischer projections ...
L-Ribose Fischer Projection. Ribose is a simple sugar and carbohydrate with molecular formula C 5 H 10 O 5 and the linear-form composition H−(C=O)−(CHOH) 4 −H. The naturally occurring form, d-ribose, is a component of the ribonucleotides from which RNA is built, and so this compound is necessary for coding, decoding, regulation and expression of genes.
As is depicted in a Fischer projection of D-threose, the adjacent substituents will have a syn orientation in the isomer referred to as "threo", and are anti in the isomer referred to as "erythro". [3] [4] Fischer projections depicting the two enantiomers of threose
Several isomers exist with the formula H−(C=O)−(CH 2)−(CHOH) 3 −H, but in deoxyribose all the hydroxyl groups are on the same side in the Fischer projection.The term "2-deoxyribose" may refer to either of two enantiomers: the biologically important d-2-deoxyribose and to the rarely encountered mirror image l-2-deoxyribose.
Hermann Emil Louis Fischer FRS FRSE FCS (German pronunciation: [ˈeːmiːl ˈfɪʃɐ] ⓘ; 9 October 1852 – 15 July 1919) was a German chemist and 1902 recipient of the Nobel Prize in Chemistry. He discovered the Fischer esterification. He also developed the Fischer projection, a symbolic way of drawing asymmetric carbon atoms. He also ...
Glucose (before oxidization) The Fischer projections of D-glucose (left) and D-glucuronic acid (right). Glucose's terminal carbon's primary alcohol group has been oxidized to a carboxylic acid. Uronic acids (/ ʊ ˈ r ɒ n ɪ k /) or alduronic acids are a class of sugar acids with both carbonyl and carboxylic acid functional groups. [1]
Fischer projection of D-glyceraldehyde. Like most carbohydrates, simple aldoses have the general chemical formula C n (H 2 O) n.Because formaldehyde (n=1) and glycolaldehyde (n=2) are not generally considered to be carbohydrates, [1] the simplest possible aldose is the triose glyceraldehyde, which only contains three carbon atoms.
More formally stated, then, an anomer is an epimer at the hemiacetal/hemiketal carbon atom in a cyclic saccharide. [1] Anomerization is the process of conversion of one anomer to the other. As is typical for stereoisomeric compounds, different anomers have different physical properties, melting points and specific rotations.