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This page shows the electron configurations of the neutral gaseous atoms in their ground states. For each atom the subshells are given first in concise form, then with all subshells written out, followed by the number of electrons per shell. For phosphorus (element 15) as an example, the concise form is [Ne] 3s 2 3p 3.
Chlorine has the electron configuration [Ne]3s 2 3p 5, with the seven electrons in the third and outermost shell acting as its valence electrons. Like all halogens, it is thus one electron short of a full octet, and is hence a strong oxidising agent, reacting with many elements in order to complete its outer shell. [39]
In each term of an electron configuration, n is the positive integer that precedes each orbital letter (helium's electron configuration is 1s 2, therefore n = 1, and the orbital contains two electrons). An atom's nth electron shell can accommodate 2n 2 electrons. For example, the first shell can accommodate two electrons, the second shell eight ...
Note that these electron configurations are given for neutral atoms in the gas phase, which are not the same as the electron configurations for the same atoms in chemical environments. In many cases, multiple configurations are within a small range of energies and the small irregularities that arise in the d- and f-blocks are quite irrelevant ...
In these structures, each atom is surrounded by seven or eight electrons. Brockway says that the three-electron bond is equivalent to half a single bond. This gives a total of two and a half single bonds in the molecule, not two double bonds or a double bond plus one and a half single bonds as in this diagram.
In chemistry and atomic physics, an electron shell may be thought of as an orbit that electrons follow around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on further and further from the nucleus.
Core charge can also be calculated as 'atomic number' minus 'all electrons except those in the outer shell'. For example, chlorine (element 17), with electron configuration 1s 2 2s 2 2p 6 3s 2 3p 5, has 17 protons and 10 inner shell electrons (2 in the first shell, and 8 in the second) so: Core charge = 17 − 10 = +7
The HF electron configuration 1σ 2 2σ 2 3σ 2 1π 4 reflects that the other electrons remain in three lone pairs and that the bond order is 1. The more electronegative atom is the more energetically excited because it more similar in energy to its atomic orbital.