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Calcium hypochlorite is a general oxidizing agent and therefore finds some use in organic chemistry. [6] For instance the compound is used to cleave glycols, α-hydroxy carboxylic acids and keto acids to yield fragmented aldehydes or carboxylic acids. [7] Calcium hypochlorite can also be used in the haloform reaction to manufacture chloroform. [8]
Shortly thereafter, Major William J. L. Lyster of the Army Medical Department used a solution of calcium hypochlorite in a linen bag to treat water. For many decades, Lyster's method remained the standard for U.S. ground forces in the field and in camps, implemented in the form of the familiar Lyster Bag (also spelled Lister Bag).
This was not simply modern calcium chloride, but contained chlorine gas dissolved in lime-water (dilute calcium hydroxide) to form calcium hypochlorite (chlorinated lime). The chlorination of the water supply helped stop the epidemic and as a precaution, the chlorination was continued until 1911 when a new water supply was commissioned. [7]
Hypochlorite salts formed by the reaction between chlorine and alkali and alkaline earth metal hydroxides. The reaction is performed at close to room temperature to suppress the formation of chlorates. This process is widely used for the industrial production of sodium hypochlorite (NaClO) and calcium hypochlorite (Ca(ClO) 2).
The disinfecting stage is optional, and is used where a sterile effluent is required, such as cases where the effluent is distributed above ground. The disinfectant typically used is tablets of calcium hypochlorite, which are specially made for waste treatment systems. [3] The tablets are intended to break down quickly in sunlight.
A purer, more stable form of calcium hypochlorite is called HTH or high test hypochlorite. It is also available as bleaching tablets that contain calcium hypochlorite and other ingredients to prevent the tablets from crumbling. A supposedly more stable mixture of calcium hypochlorite and quicklime (calcium oxide) is known as "tropical bleach". [22]
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