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tert-Butyl chloride is the organochloride with the formula (CH 3) 3 CCl. It is a colorless, flammable liquid. It is sparingly soluble in water, with a tendency to undergo hydrolysis to the corresponding tert-butyl alcohol. It is produced industrially as a precursor to other organic compounds. [1]
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
tert-Butyl chloride (2-chloro-2-methylpropane) This page was last edited on 25 November 2020, at 11:39 (UTC). Text is available under the Creative Commons Attribution ...
tert-Butyldimethylsilyl chloride is an organosilicon compound with the formula (Me 3 C)Me 2 SiCl (Me = CH 3). It is commonly abbreviated as TBSCl or TBDMSCl. It is a chlorosilane containing two methyl groups and a tert-butyl group. As such it is more bulky that trimethylsilyl chloride. It is a colorless or white solid that is soluble in many ...
With tert-butyl chloride Et 2 AlCl abstracts a chlorine atom to form the tert-butyl carbocation as the electrophile. Efficient initiators that resemble the monomer are called cationogens . Termination and chain transfer are minimized when the initiator counterion is both non-nucleophilic and non-basic.
The substitution reaction of tert-Butyl chloride was chosen as reference reaction. The first step, ionizing step, is the rate determining step, SO stands for the nucleophilic solvent. The reference solvent is 80% Ethanol and 20% water by volume. Both of them can carry out the nucleophilic attack on the carbocation.
tert-Butyl alcohol is used as a solvent, ethanol denaturant, paint remover ingredient, and gasoline octane booster and oxygenate.It is a chemical intermediate used to produce methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by reaction with methanol and ethanol, respectively, and tert-butyl hydroperoxide (TBHP) by reaction with hydrogen peroxide.
tert-Butyl hypochlorite is the organic compound with the formula (CH 3) 3 COCl. A yellow liquid, it is a rare example of an organic hypochlorite, i.e. a compound with an O-Cl bond. It is a reactive material that is useful for chlorinations. It can be viewed as a lipophilic version of sodium hypochlorite (bleach). [1]