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The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The calorific value is the total energy released as heat when a substance undergoes complete combustion with oxygen under standard conditions.
All values refer to 25 °C and to the thermodynamically stable standard state at that temperature unless noted. Values from CRC refer to "100 kPa (1 bar or 0.987 standard atmospheres)". Lange indirectly defines the values to be standard atmosphere of "1 atm (101325 Pa)", although citing the same NBS and JANAF sources among others.
Unless otherwise stated, the values in the following table are lower heating values for perfect combustion, not counting oxidizer mass or volume. When used to produce electricity in a fuel cell or to do work, it is the Gibbs free energy of reaction (ΔG) that sets the theoretical upper limit.
The calorific value Q of coal [kJ/kg] is the heat liberated by its complete combustion with oxygen. Q is a complex function of the elemental composition of the coal [citation needed]. Q can be determined experimentally using calorimeters. Dulong suggests the following approximate formula for Q when the oxygen content is less than 10%:
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
Gaseous fuels like methane have higher values than solid fuels like coal. Peat exhibits the lowest value of all common fuels. Thus methane has an HHV (Higher heating value) of 55.50 MJ/kg, the highest value of common fuels. Diesel fuel has an HHV value of 44.80 MJ/kg and anthracite coal a value of 32.50 MJ/kg.
The products from the air cycle contain non-calorific nitrogen and are exhausted out the stack while the products of the steam cycle are kept as blue water gas. This gas is composed almost entirely of CO and H 2, and burns with a pale blue flame similar to natural gas. BWG has a calorific value of 11 MJ/m 3 (300 BTU/cu ft).
LPG has a typical specific calorific value of 46.1 MJ/kg compared with 42.5 MJ/kg for fuel oil and 43.5 MJ/kg for premium grade petrol (gasoline). [14] However, its energy density per volume unit of 26 MJ/L is lower than either that of petrol or fuel oil, as its relative density is lower (about 0.5–0.58 kg/L, compared to 0.71–0.77 kg/L for ...