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Liquid nitrogen is a compact and readily transported source of dry nitrogen gas, as it does not require pressurization. Further, its ability to maintain temperatures far below the freezing point of water, specific heat of 1040 J ⋅kg -1 ⋅K -1 and heat of vaporization of 200 kJ⋅kg -1 makes it extremely useful in a wide range of applications ...
Argon has approximately the same solubility in water as oxygen and is 2.5 times more soluble in water than nitrogen. Argon is colorless, odorless, nonflammable and nontoxic as a solid, liquid or gas. [11] Argon is chemically inert under most conditions and forms no confirmed stable compounds at room temperature.
Though argon is present in less to 1% of the incoming, the air argon column requires a significant amount of energy due to the high reflux ratio required (about 30) in the argon column. Cooling of the argon column can be supplied from cold expanded rich liquid or by liquid nitrogen.
If a sufficient amount of liquid is vaporized within a closed container, it produces pressures that can rupture the pressure vessel. Hence the use of pressure relief valves and vent valves are important. [2] The expansion ratio of liquefied and cryogenic from the boiling point to ambient is: nitrogen – 1 to 696; liquid helium – 1 to 745 ...
Liquid nitrogen. Liquefaction of gases is physical conversion of a gas into a liquid state (condensation). The liquefaction of gases is a complicated process that uses various compressions and expansions to achieve high pressures and very low temperatures, using, for example, turboexpanders.
Because the liquid-to-gas expansion ratio of nitrogen is 1:694 at 20 °C, a tremendous amount of force can be generated if liquid nitrogen is rapidly vaporised in an enclosed space. In an incident on January 12, 2006, at Texas A&M University , the pressure-relief devices of a tank of liquid nitrogen were malfunctioning and later sealed.
David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition.CRC Press. Boca Raton, Florida, 2003; Section 6, Fluid Properties; Vapor Pressure Uncertainties of several degrees should generally be assumed.
The gaseous state of water is lighter than air (density 0.804 g/L at STP, average molecular mass 18.015 g/mol) due to water's low molar mass when compared with typical atmospheric gases such as nitrogen gas (N 2). It is non-flammable and much cheaper than helium. The concept of using steam for lifting is therefore already 200 years old.
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