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1,4-Dioxane (/ d aɪ ˈ ɒ k s eɪ n /) is a heterocyclic organic compound, classified as an ether. It is a colorless liquid with a faint sweet odor similar to that of diethyl ether . The compound is often called simply dioxane because the other dioxane isomers ( 1,2- and 1,3- ) are rarely encountered.
1,3-Dioxane or m-dioxane is an organic compound with the molecular formula (CH 2) 4 O 2. It is a saturated six-membered heterocycle with two oxygen atoms in place of carbon atoms at the 1- and 3- positions. 1,4-Dioxane, which is of greater commercial value, is an isomer. Both dioxanes are colorless liquids. [1]
1,2-Dioxane or o-dioxane is an organic compound with the molecular formula (CH 2) 4 O 2, classified as a cyclic peroxide.
Dioxane may refer to the following chemical compounds: 1,2-dioxane; 1,3-dioxane; 1,4-dioxane This page was last edited on 13 October 2023, at 00:57 (UTC). Text is ...
Substituents in ortho-positions 2 and 6 prevent rotation and thus hinder the molecule from assuming a planar position. Mono-ortho congeners (one Cl in 2, 2', 6, or 6') have minimal activity. No significant dioxin-like activities have been noticed, if there are two or more o-chlorines. [ 5 ]
The benzodioxans are a group of isomeric chemical compounds with the molecular formula C 8 H 8 O 2. [1] There are three isomers of benzodioxan, as the second atom of oxygen of the dioxane can be in a second, third or fourth position: 1,2-dioxane, 1,3-dioxane and 1,4-dioxane, which respectively give 1,2-benzodioxan, 1,3-benzodioxan and 1,4-benzodioxan.
Grignard reagents react with 1,4-dioxane to give the diorganomagnesium compounds and insoluble coordination polymer MgX 2 (dioxane) 2 and (R = organic group, X = halide): 2 RMgX + dioxane ⇌ R 2 Mg + MgX 2 (dioxane) 2. This reaction exploits the Schlenk equilibrium, driving it toward the right.
The structure of gas-phase molecular GeCl 2 shows that it is a bent molecule, as predicted by VSEPR theory. [5] The dioxane complex, GeCl 2 ·dioxane, has been used as a source of molecular GeCl 2 for reaction syntheses, as has the in situ reaction of GeCl 4 and Ge metal. GeCl 2 is quite reactive and inserts into many types of chemical bonds. [6]