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  2. Propiolaldehyde - Wikipedia

    en.wikipedia.org/wiki/Propiolaldehyde

    0.9152 g/cm 3: Boiling point: 54–57 °C (129–135 °F; 327–330 K) ... Its acetal can be prepared from acrolein. [2] Occurrence in interstellar medium

  3. Azeotrope tables - Wikipedia

    en.wikipedia.org/wiki/Azeotrope_tables

    This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.

  4. Knoevenagel condensation - Wikipedia

    en.wikipedia.org/wiki/Knoevenagel_condensation

    The active hydrogen component has the forms: [3] Z−CH 2 −Z or Z−CHR−Z for instance diethyl malonate, Meldrum's acid, ethyl acetoacetate or malonic acid, or cyanoacetic acid. [1] Z−CHRR', for instance nitromethane. where Z is an electron withdrawing group. Z must be powerful enough to facilitate deprotonation to the enolate ion even ...

  5. Propionaldehyde - Wikipedia

    en.wikipedia.org/wiki/Propionaldehyde

    Propionaldehyde exhibits the reactions characteristic of alkyl aldehydes, e.g. hydrogenation, aldol condensations, oxidations, etc. It is the simplest aldehyde with a prochiral methylene such that α-functionalized derivatives (CH 3 CH(X)CHO) are chiral. If water is available, propionaldehyde exists in equilibrium with 1,1-propanediol, a ...

  6. Acrolein - Wikipedia

    en.wikipedia.org/wiki/Acrolein

    Acrolein (systematic name: propenal) is the simplest unsaturated aldehyde.It is a colorless liquid with a foul and acrid aroma. The smell of burnt fat (as when cooking oil is heated to its smoke point) is caused by glycerol in the burning fat breaking down into acrolein.

  7. Knorr pyrrole synthesis - Wikipedia

    en.wikipedia.org/wiki/Knorr_pyrrole_synthesis

    The resulting product, diethyl 3,5-dimethylpyrrole-2,4-dicarboxylate, has been called Knorr's Pyrrole ever since. In the Scheme above, R 2 = COOEt, and R 1 = R 3 = Me represent this original reaction. Knorr's pyrrole can be derivatized in a number of useful manners. One equivalent of sodium hydroxide will saponify the 2

  8. Propionitrile - Wikipedia

    en.wikipedia.org/wiki/Propionitrile

    ch 3 ch 2 ch 2 oh + o 2 + nh 3 → ch 3 ch 2 c≡n + 3 h 2 o Propionitrile is a byproduct of the electrodimerisation of acrylonitrile to adiponitrile . In the laboratory propanenitrile can also be produced by the dehydration of propionamide , by catalytic reduction of acrylonitrile , or by distilling ethyl sulfate and potassium cyanide .

  9. Acetaldehyde - Wikipedia

    en.wikipedia.org/wiki/Acetaldehyde

    The product, CH 3 CH(OCH 2 CH 3) 2, is formally named 1,1-diethoxyethane but is commonly referred to as "acetal". [39] This can cause confusion as "acetal" is more commonly used to describe compounds with the functional groups RCH(OR') 2 or RR'C(OR'') 2 rather than referring to this specific compound — in fact, 1,1-diethoxyethane is also ...