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Nucleophilic substitution via the S N 1 or S N 2 mechanism does not generally occur with vinyl or aryl halides or related compounds. Under certain conditions nucleophilic substitutions may occur, via other mechanisms such as those described in the nucleophilic aromatic substitution article.
The unimolecular nucleophilic substitution (S N 1) reaction is a substitution reaction in organic chemistry. The Hughes-Ingold symbol of the mechanism expresses two properties—"S N " stands for " nucleophilic substitution ", and the "1" says that the rate-determining step is unimolecular .
In chemistry, S N i (substitution nucleophilic internal) refers to a specific, regio-selective but not often encountered reaction mechanism for nucleophilic aliphatic substitution. The name was introduced by Cowdrey et al. in 1937 to label nucleophilic reactions which occur with retention of configuration, [ 1 ] but later was employed to ...
A nucleophilic aromatic substitution (S N Ar) is a substitution reaction in organic chemistry in which the nucleophile displaces a good leaving group, such as a halide, on an aromatic ring. Aromatic rings are usually nucleophilic, but some aromatic compounds do undergo nucleophilic substitution.
The bimolecular nucleophilic substitution (S N 2) is a type of reaction mechanism that is common in organic chemistry. In the S N 2 reaction, a strong nucleophile forms a new bond to an sp 3 -hybridised carbon atom via a backside attack, all while the leaving group detaches from the reaction center in a concerted (i.e. simultaneous) fashion.
Pages in category "Nucleophilic substitution reactions" The following 7 pages are in this category, out of 7 total. This list may not reflect recent changes. ...
Neutral nucleophilic reactions with solvents such as alcohols and water are named solvolysis. Nucleophiles may take part in nucleophilic substitution, whereby a nucleophile becomes attracted to a full or partial positive charge, and nucleophilic addition. Nucleophilicity is closely related to basicity.
Ammonolysis refers to solvolysis by ammonia, but can also describe nucleophilic attack by ammonia more generally. Ammonia boils at −33 °C, and, as such, is rarely used as a solvent in its pure form. It is, however, readily miscible with water, and is commonly used in the form of a saturated aqueous solution. For this reason, ammonolysis may ...