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In organic chemistry, an alkene, or olefin, is a hydrocarbon containing a carbon–carbon double bond. [1] The double bond may be internal or in the terminal position.
There are two types of alpha-olefins, branched and linear (or normal). The chemical properties of branched alpha-olefins with a branch at either the second (vinylidene) or the third carbon number are significantly different from the properties of linear alpha-olefins and those with branches on the fourth carbon number and further from the start of the chain.
It is usually encountered as a solution in solvents, commonly toluene but also xylene, cumene, or mesitylene, [1] Used in large excess, it activates precatalysts for alkene polymerization. [ 2 ] [ 3 ] [ 4 ]
An enal (or alkenal) is an organic compound containing both alkene and aldehyde functional groups. In an α,β-unsaturated enal, the alkene is conjugated to the carbonyl group of the aldehyde (formyl group). [3] The simplest enal is acrolein (CH 2 =CHCHO). Other examples include cis-3-hexenal (essence of mowed lawns) and cinnamaldehyde (essence ...
Allene exists in equilibrium with methylacetylene (propyne) and the mixture is sometimes called MAPD for methylacetylene-propadiene: . H 3 CC≡CH ⇌ H 2 C=C=CH 2. for which K eq = 0.22 at 270 °C or 0.1 at 5 °C.
In organic chemistry, a rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural isomer of the original molecule. [1] Often a substituent moves from one atom to another atom in the same molecule, hence these reactions are usually intramolecular. In the example below ...
Straight-chain terminal alkenes, also called linear alpha olefins (LAO) or normal alpha olefins (NAO), are alkenes (olefins) having a chemical formula C n H 2n, distinguished from other alkenes with a similar molecular formula by being terminal alkenes, in which the double bond occurs at the alpha (α-, 1-or primary) position, and by having a linear (unbranched) hydrocarbon chain.
In organic chemistry, an addition reaction is an organic reaction in which two or more molecules combine to form a larger molecule called the adduct. [1] [2] An addition reaction is limited to chemical compounds that have multiple bonds. Examples include a molecule with a carbon–carbon double bond (an alkene) or a triple bond (an alkyne).