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In colloidal and surface chemistry, the critical micelle concentration (CMC) is defined as the concentration of surfactants above which micelles form and all additional surfactants added to the system will form micelles. [1] The CMC is an important characteristic of a surfactant.
In colloidal chemistry, the critical micelle concentration (CMC) of a surfactant is one of the parameters in the Gibbs free energy of micellization. The concentration at which the monomeric surfactants self-assemble into thermodynamically stable aggregates is the CMC.
The critical micelle concentration (CMC) in water at 25 °C is 8.2 mM, [1] and the aggregation number at this concentration is usually considered to be about 62. [3] The micelle ionization fraction (α) is around 0.3 (or 30%). [4]
Polymeric micelles have a much lower critical micellar concentration (CMC) than soap (0.0001 to 0.001 mol/L) or surfactant micelles, but are nevertheless at equilibrium with isolated macromolecules called unimers. Therefore, micelle formation and stability are concentration-dependent. [3]
CM is the concentration of the micelle in the mobile phase (total surfactant concentration - critical micelle concentration) A plot of 1/k¢ verses CM gives a straight line in which KSW can be calculated from the intercept and KMW can be obtained from the ratio of the slope to the intercept. Finally, KSM can be obtained from the ratio of the ...
Micellar solutions form when the concentration of amphiphile exceeds the critical micelle concentration (CMC) or critical aggregation concentration (CAC), which is when there are enough amphiphiles in the solution to clump together to form micells.
Below the Krafft temperature, the maximum solubility of the surfactant will be lower than the critical micelle concentration, meaning micelles will not form. The Krafft temperature is a point of phase change below which the surfactant remains in crystalline form, even in an aqueous solution.
In colloidal chemistry, an aggregation number is a description of the number of molecules present in a micelle once the critical micelle concentration (CMC) has been reached. In more detail, it has been defined as the average number of surfactant monomers in a spherical micelle. [1]