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Sulfates of Group (II) metal ions (M 2+), generally decrease in solubility down the group. The most difficult scales to remove are those of Barium sulfate because of its high insolubility forming very hard scale deposits. A general representation of the reaction is summarized in reaction: 5.
The solubility of a specific solute in a specific solvent is generally expressed as the concentration of a saturated solution of the two. [1] Any of the several ways of expressing concentration of solutions can be used, such as the mass, volume, or amount in moles of the solute for a specific mass, volume, or mole amount of the solvent or of the solution.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
A solubility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution containing the compound. This type of equilibrium is an example of dynamic equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another.
Note the decrease in ΔG ‡ activation for the polar-solvent reaction conditions. This arises from the fact that polar solvents stabilize the formation of the carbocation intermediate to a greater extent than the non-polar-solvent conditions. This is apparent in the ΔE a, ΔΔG ‡ activation. On the right is an S N 2 reaction
In masonry, sulfates produced by the oxidation of pyrite in clay materials can be present in bricks. They are gradually released over a long period of time, causing sulfate attack of mortar, especially where moisture movement concentrates the sulfates. [4] Seawater: sulfate is the second anion present in seawater after chloride.
Alkyl sulfates if ingested are well-absorbed and are metabolized into a C 3, C 4 or C 5 sulfate and an additional metabolite. The highest irritant of the alkyl sulfates is sodium laurylsulfate, with the threshold before irritation at a concentration of 20%. Surfactants in consumer products are typically mixed, reducing likelihood of irritation.