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Hydrogen can also be produced from water and electricity using electrolysis: at one time, most of Europe's ammonia was produced from the Hydro plant at Vemork. Other possibilities include biological hydrogen production or photolysis, but at present, steam reforming of natural gas is the most economical means of mass-producing hydrogen.
Ammonia is produced biologically in a process called nitrogen fixation, but even more is generated industrially by the Haber process. The process helped revolutionize agriculture by providing cheap fertilizers. The global industrial production of ammonia in 2021 was 235 million tonnes.
The dominant industrial method for producing ammonia is the Haber process also known as the Haber-Bosch process. [76] Fertilizer production is now the largest source of human-produced fixed nitrogen in the terrestrial ecosystem. Ammonia is a required precursor to fertilizers, explosives, and other products. The Haber process requires high ...
In the 1870s, ammonia was an unwanted byproduct of making manufactured gas. Its importance emerged later, and in the 1900s the industry modified their facilities to produce it from coke. Still, production could not meet demand. [25] In 1900, Chile, with its deposits of saltpeter, produced two-thirds of all fertilizer on the planet. [26]
Ammonia electrolysis may require much less thermodynamic energy than water electrolysis (only 0.06 V in alkaline media). [23] Another option for recovering ammonia from wastewater is to use the mechanics of the ammonia-water thermal absorption cycle. [24] [25] Ammonia can thus be recovered either as a liquid or as ammonium hydroxide. The ...
Oxygen is produced by plants and some bacteria in photosynthesis, while CO 2 is a waste product of all animals and plants. Nitrogen gases are produced by denitrifying bacteria and as a waste product, and bacteria for decaying yield ammonia, as do most invertebrates and vertebrates.
In the early decades of the 20th century, the Nobel Prize-winning chemists Carl Bosch of IG Farben and Fritz Haber developed the Haber process [15] which utilized molecular nitrogen (N 2) and methane (CH 4) gas in an economically sustainable synthesis of ammonia (NH 3). The ammonia produced in the Haber process is the main raw material of the ...
The industrial production of ammonium nitrate entails the acid-base reaction of ammonia with nitric acid: [12] HNO 3 + NH 3 → NH 4 NO 3. The ammonia required for this process is obtained by the Haber process from nitrogen and hydrogen. Ammonia produced by the Haber process can be oxidized to nitric acid by the Ostwald process.