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Permanganic acid (or manganic(VII) acid) is the inorganic compound with the formula H MnO 4 and various hydrates. [3] This strong oxoacid has been isolated as its dihydrate. It is the conjugate acid of permanganate salts. It is the subject of few publications and its characterization as well as its uses are very limited.
4, the conjugate base of permanganic acid. Because the manganese atom has a +7 oxidation state, the permanganate(VII) ion is a strong oxidising agent. The ion is a transition metal ion with a tetrahedral structure. [2] Permanganate solutions are purple in colour and are stable in neutral or slightly alkaline media. The exact chemical reaction ...
The reaction initially produces permanganic acid, HMnO 4 (structurally, HOMnO 3), which is dehydrated by cold sulfuric acid to form its anhydride, Mn 2 O 7: 2 KMnO 4 + 2 H 2 SO 4 → Mn 2 O 7 + H 2 O + 2 KHSO 4. Mn 2 O 7 can react further with sulfuric acid to give the remarkable manganyl(VII) cation MnO + 3, which is isoelectronic with CrO 3:
A weak acid such as carbonic acid is sufficient for this reaction: 3 K 2 MnO 4 + 2 CO 2 2 KMnO 4 + 2 K 2 CO 3 + MnO 2 {\displaystyle {\ce {3 K2MnO4 + 2 CO2 -> 2 KMnO4 + 2 K2CO3 + MnO2}}} Permanganate salts may also be generated by treating a solution of Mn 2+ ions with strong oxidants such as lead dioxide (PbO 2 ), sodium bismuthate (NaBiO 3 ...
Uses include for fungal infections of the foot, impetigo, pemphigus, superficial wounds, dermatitis (eczema), and tropical ulcers. [3] [2] Typically it is used in skin conditions that produce a lot of liquid. [3] For tropical ulcers it is used together with procaine benzylpenicillin for two to four weeks. [2] [8] It can be used in children and ...
The V-2 rocket used it in combination with hydrogen peroxide to drive a steam turbopump. [ 3 ] As an oxidizer, sodium permanganate is used in environmental remediation of soil and groundwater contaminated with chlorinated solvents using the remediation technology in situ chemical oxidation, also referred to as ISCO.
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Permanganic acid can be prepared by the reaction of dilute sulfuric acid with a solution barium permanganate, the insoluble barium sulfate byproduct being removed by filtering: [3] Ba(MnO 4) 2 + H 2 SO 4 → 2 HMnO 4 + BaSO 4. The sulfuric acid used must be dilute; reactions of permanganates with concentrated sulfuric acid yield the anhydride ...