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Lewis dot structure of a Hydroxide ion compared to a hydroxyl radical. In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. [1] [2] With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most ...
The hydroxyl radical can damage virtually all types of macromolecules: carbohydrates, nucleic acids , lipids (lipid peroxidation) and amino acids (e.g. conversion of Phe to m-Tyrosine and o-Tyrosine). The hydroxyl radical has a very short in vivo half-life of approximately 10 −9 seconds and a high reactivity. [5]
A trivalent group 14 radical (also known as a trivalent tetrel radical) is a molecule that contains a group 14 element (E = C, Si, Ge, Sn, Pb) with three bonds and a free radical, having the general formula of R 3 E•. Such compounds can be categorized into three different types, depending on the structure (or equivalently the orbital in which ...
The free radicals generated by this process engage in secondary reactions. For example, the hydroxyl is a powerful, non-selective oxidant. [6] Oxidation of an organic compound by Fenton's reagent is rapid and exothermic and results in the oxidation of contaminants to primarily carbon dioxide and water.
Dissociation in chemistry is a general process in which molecules (or ionic compounds such as salts, or complexes) separate or split into other things such as atoms, ions, or radicals, usually in a reversible manner.
[7] [8] Ansylyn and Dougherty explained in simple terms how the group increments, or Benson increments, are derived from experimental calculations. [9] By calculating the ΔΔ f H between extended saturated alkyl chains (which is just the difference between two Δ f H values), as shown in the table, one can approximate the value of the C−(C ...
Download as PDF; Printable version; In other projects ... Pages in category "Free radicals" ... Free radical; Radical (chemistry) * Disposable soma theory of aging ...
Chain propagation: A radical reacts with a non-radical to produce a new radical species; Chain termination: Two radicals react with each other to create a non-radical species; In a free-radical addition, there are two chain propagation steps. In one, the adding radical attaches to a multiply-bonded precursor to give a radical with lesser bond ...