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Enantiotopic groups are identical and indistinguishable except in chiral environments. For instance, the CH 2 hydrogens in ethanol (CH 3 CH 2 OH) are normally enantiotopic, but can be made different (diastereotopic) if combined with a chiral center, for instance by conversion to an ester of a chiral carboxylic acid such as lactic acid, or if coordinated to a chiral metal center, or if ...
Representation of an organic compound hydroxy group, where R represents a hydrocarbon or other organic moiety, the red and grey spheres represent oxygen and hydrogen atoms respectively, and the rod-like connections between these, covalent chemical bonds. In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula ...
When necessary, the position of the hydroxyl group is indicated by a number between the alkane name and the -ol: propan-1-ol for CH 3 CH 2 CH 2 OH, propan-2-ol for CH 3 CH(OH)CH 3. If a higher priority group is present (such as an aldehyde , ketone , or carboxylic acid ), then the prefix hydroxy- is used, [ 19 ] e.g., as in 1-hydroxy-2 ...
RRC=CH 2 + H 2 O → RRC(OH)-CH 3. A hydroxyl group (OH −) attaches to one carbon of the double bond, and a proton (H +) adds to the other. The reaction is highly exothermic. In the first step, the alkene acts as a nucleophile and attacks the proton, following Markovnikov's rule. In the second step an H 2 O molecule bonds to the other, more
Ringer's lactate solution is an example where the conjugate base of an organic acid, lactic acid, CH 3 CH(OH)CO − 2 is combined with sodium, calcium and potassium cations and chloride anions in distilled water [ 4 ] which together form a fluid which is isotonic in relation to human blood and is used for fluid resuscitation after blood loss ...
If the two 1s orbitals are not in phase, a node between them causes a jump in energy, the σ* orbital. From the diagram you can deduce the bond order, how many bonds are formed between the two atoms. For this molecule it is equal to one. Bond order can also give insight to how close or stretched a bond has become if a molecule is ionized. [12]
The pK a of 3−ClC 6 H 4)Si(CH 3) 2 OH is 11. [3] Because of their greater acidity, silanols can be fully deprotonated in aqueous solution, especially the arylsilanols. The conjugate base is called a siloxide or a silanolate. Despite the disparity in acidity, the basicities of alkoxides and siloxides are similar. [3]
Arrow pushing or electron pushing is a technique used to describe the progression of organic chemistry reaction mechanisms. [1] It was first developed by Sir Robert Robinson.In using arrow pushing, "curved arrows" or "curly arrows" are drawn on the structural formulae of reactants in a chemical equation to show the reaction mechanism.